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典型文献
Kinetics of the hydrogen absorption and desorption processes of hydrogen storage alloys: A review
文献摘要:
High hydrogen absorption and desorption rates are two significant index parameters for the applications of hydrogen storage tanks. The analysis of the hydrogen absorption and desorption behavior using the isothermal kinetic models is an efficient way to investigate the kin-etic mechanism. Multitudinous kinetic models have been developed to describe the kinetic process. However, these kinetic models were de-duced based on some assumptions and only appropriate for specific kinetic measurement methods and rate-controlling steps (RCSs), which sometimes lead to confusion during application. The kinetic analysis procedures using these kinetic models, as well as the key kinetic paramet-ers, are unclear for many researchers who are unfamiliar with this field. These problems will prevent the kinetic models and their analysis methods from revealing the kinetic mechanism of hydrogen storage alloys. Thus, this review mainly focuses on the summarization of kinetic models based on different kinetic measurement methods and RCSs for the chemisorption, surface penetration, diffusion of hydrogen, nucle-ation and growth, and chemical reaction processes. The analysis procedures of kinetic experimental data are expounded, as well as the effects of temperature, hydrogen pressure, and particle radius. The applications of the kinetic models for different hydrogen storage alloys are also in-troduced.
文献关键词:
作者姓名:
Qian Li;Xi Lin;Qun Luo;Yu?an Chen;Jingfeng Wang;Bin Jiang;Fusheng Pan
作者机构:
National Engineering Research Center for Magnesium Alloys, Chongqing University, Chongqing 400044, China;State Key Laboratory of Advanced Special Steels & Shanghai Key Laboratory of Advanced Ferrometallurgy & School of Materials Science and Engineering,Shanghai University, Shanghai 200444, China;School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
引用格式:
[1]Qian Li;Xi Lin;Qun Luo;Yu?an Chen;Jingfeng Wang;Bin Jiang;Fusheng Pan-.Kinetics of the hydrogen absorption and desorption processes of hydrogen storage alloys: A review)[J].矿物冶金与材料学报,2022(01):32-48
A类:
Multitudinous,RCSs
B类:
Kinetics,hydrogen,absorption,desorption,processes,storage,alloys,review,High,rates,are,two,significant,parameters,applications,tanks,analysis,behavior,using,isothermal,kinetic,models,efficient,way,investigate,mechanism,have,been,developed,describe,However,these,were,assumptions,only,appropriate,specific,measurement,methods,controlling,steps,which,sometimes,lead,confusion,during,procedures,well,key,unclear,many,researchers,who,unfamiliar,this,field,These,problems,will,prevent,their,from,revealing,Thus,mainly,focuses,summarization,different,chemisorption,surface,penetration,diffusion,nucle,growth,chemical,reaction,experimental,data,expounded,effects,temperature,pressure,particle,radius,also,troduced
AB值:
0.452876
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