典型文献
Unique capability of NdPO4 to activate hydrogen for efficient hydrogenation of furfural to furfuryl alcohol over Nd-Co-P composites
文献摘要：
Efficient and applicable catalysts are highly desirable for advanced biomass transformation industry,here,we fabricated a series of Nd-Co-P catalysts for hydrogenation of furfural(FAL)to furfuryl alcohol(FOH).By comprehensive characterizations,it is demonstrated that the prepared Nd-Co-P samples are structured as(NdPO4)m/Co2P nanocomposites with molar ratio(m)in range of 0.24-1.1;by manipulating m,the outstanding catalytic efficiency comparable with the performance of precious metal catalysts,such as turnover frequency(TOF)up to 0.50 s-1(being ten-fold higher than Co2P)and FOH yield up to 97％,is achieved on the reusable(NdPO4)m/Co2P composites.Temperature programmed desorption(TPD),in-situ infrared spectroscopy(IR)and kinetic-mechanism studies further disclose that Co2P is decisive for activating FAL,instead,NdPO4 possesses unique capability of activating hydrogen which readily facilitate the selective hydrogenation of FAL to FOH through a rapid Langmuir-Hinshelwood process over(NdPO4)m/Co2P catalyst.These results indicate that rare-earth phosphates like NdPO4 can act as the promising and reliable catalytic component to activate hydrogen,which can be of interest not only for innovating novel and applicable non-metallic catalysts for sustainable biomass transformation analogous to hydrogenation of FAL but also for expanding material base for other green mass transformation techniques involving hydrogen.
文献关键词：
中图分类号：
作者姓名：
Xianghua He;Ben Dai;Yafang Zhang;Dan Zhao;Dihui Zhang;Ruping Liang;Chao Chen
作者机构：
Key Laboratory of Jiangxi Province for Environment and Energy Catalysis,College of Chemistry,Nanchang University,Nanchang 330031,China
文献出处：
引用格式：
[1]Xianghua He;Ben Dai;Yafang Zhang;Dan Zhao;Dihui Zhang;Ruping Liang;Chao Chen-.Unique capability of NdPO4 to activate hydrogen for efficient hydrogenation of furfural to furfuryl alcohol over Nd-Co-P composites)[J].稀土学报（英文版）,2022(07):1073-1082
A类：
NdPO4,FOH
B类：
Unique,capability,activate,efficient,hydrogenation,furfural,furfuryl,alcohol,Efficient,applicable,catalysts,highly,desirable,advanced,biomass,transformation,industry,here,we,fabricated,series,FAL,By,comprehensive,characterizations,demonstrated,that,prepared,samples,structured,Co2P,nanocomposites,molar,ratio,range,by,manipulating,outstanding,catalytic,efficiency,comparable,performance,precious,such,turnover,frequency,TOF,up,being,ten,fold,higher,than,yield,achieved,reusable,Temperature,programmed,desorption,TPD,situ,infrared,spectroscopy,kinetic,mechanism,studies,further,disclose,decisive,activating,instead,possesses,unique,which,readily,facilitate,selective,through,rapid,Langmuir,Hinshelwood,process,These,results,indicate,earth,phosphates,like,can,promising,reliable,component,interest,not,only,innovating,novel,metallic,sustainable,analogous,but,also,expanding,material,base,other,green,techniques,involving
AB值：
0.529904
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
