典型文献
Polymeric partners breathe together:using gas to direct polymer self-assembly via gas-bridging chemistry
文献摘要：
The quest for a general and facile way to regulate polymer self-assembled nanostructures with low-to high-order ergodicity is an eternal theme in soft nanoparticle fabrication.Here we present an unprecedented gas-bridging strategy that allows to use gas to direct polymer self-assembly in continuous and tunable manners.Such system comprises a partner of frustrated Lewis polymers with bulky Lewis acid and base groups.They can together"breathe in"external gases to form gas-bridged structures between the two complementary moieties,which drive their mutual complexation and assemble into polymer nanoparticles of diverse geometries and dimensionalities.This strategy is applicable to a broad family of gas substances including but not limited to carbon oxides,nitrogen oxides,sulfur oxides,and even olefins;moreover,tailoring gas types and levels can dictate distinct assembling evolutionary pathways and deformable behaviors among spherical,fibrous,polymersomal,tubesomal and cubo-somal morphologies.We also discover that the gas-based bonding chemistry is the mechanistic basis underlying the phase transitional control and phase window regulation.This will open a new direction of making bespoke polymer nanostructures with gas.
文献关键词：
中图分类号：
作者姓名：
Zehao Gong;Yixin Wang;Qiang Yan
作者机构：
State Key Laboratory of Molecular Engineering of Polymers,Department of Macromolecular Science,Fudan University,200433,China
文献出处：
引用格式：
[1]Zehao Gong;Yixin Wang;Qiang Yan-.Polymeric partners breathe together:using gas to direct polymer self-assembly via gas-bridging chemistry)[J].中国科学:化学（英文版）,2022(07):1401-1410
A类：
dimensionalities,polymersomal,tubesomal,cubo
B类：
Polymeric,partners,breathe,together,using,self,assembly,via,bridging,chemistry,quest,general,facile,regulate,assembled,nanostructures,high,order,ergodicity,eternal,theme,soft,fabrication,Here,present,unprecedented,strategy,that,allows,use,continuous,tunable,manners,Such,system,comprises,frustrated,Lewis,bulky,acid,groups,They,can,external,gases,bridged,between,two,complementary,moieties,which,drive,their,mutual,complexation,into,nanoparticles,diverse,geometries,This,applicable,broad,family,substances,including,but,not,limited,carbon,oxides,nitrogen,sulfur,even,olefins,moreover,tailoring,types,levels,dictate,distinct,assembling,evolutionary,pathways,deformable,behaviors,among,spherical,fibrous,morphologies,We,also,discover,bonding,mechanistic,basis,underlying,phase,transitional,control,window,regulation,will,open,new,direction,making,bespoke
AB值：
0.621476
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