In order to mimic hierarchical nanostructures in nature,particles of polymer blends consisting of poly(4-butyltriphenylamine) (PBTPA),poly(methyl methacrylate) (PMMA) and PBTPA-block-PMMA were fabricated by a solvent evaporation method.Effects of the molecular weight and the chemical composi-tion of PBTPA-b-PMMA,molecular weights of homopolymers,and the composition of the blend on the morphology were investigated.The polymer blend particle consisting of PBTPA and PMMA homopoly-mers exhibited thermodynamically favored core-shell structure,in which more hydrophilic PMMA-shell surrounded PBTPA-core.The addition of 10 wt％ of PBTPA-b-PMMA caused the morphological transition from core-shell toJanus or inversed core-shell,in which PBTPA-shell surrounded PMMA-core,depending on the molecular weight of PBTPA segment in PBTPA-b-PMMA.When the molecular weight of PMMA segment was higher than that of PMMA homopolymer,watermelon-like particles in which small PBTPA domain less than 80 nm dispersed in the PMMA domain surrounded by PBTPA shell were observed.As the ratio of PBTPA-b-PMMA increased,the interface of the macrophase separation became obscure.At 50 wt％ of the PBTPA-b-PMMA,only microphase separation was observed.The measurement of interfa-cial tension by pendant drop method demonstrated that PBTPA-b-PMMA lower the interfacial tension between PBTPA and the aqueous phase to the value similar to that of PMMA with the aqueous phase.

Graduate School of Bio-Applications and Systems Engineering,Tokyo University of Agriculture and Technology,2-24-16 Nakacho,Koganei-shi,Tokyo 184-8588,Japan;Institute of Global Innovation Research,Tokyo University of Agriculture and Technology,2-24-16 Nakacho,Koganei-shi,Tokyo 184-8588,Japan;State Key Laboratory of Biochemical Engineering,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100080,China

[1]Shu Kikuchi;Ryoka Shoji;Shinji Kanehashi;Guanghui Ma;Kenji Ogino-.Formation of biomimetic hierarchical nanostructure in homopolymers and block copolymer ternary blend particles)[J].颗粒学报（英文版）,2022(05):98-109

homopolymers,butyltriphenylamine,PBTPA,homopoly,toJanus,macrophase

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