典型文献
β-Cyclodextrin carbon-based nanoparticles with a core-shell-shell structure for efficient adsorption of crystal violet and bisphenol A
文献摘要:
Textile wastewater contains highly toxic,nondegradable,carcinogenic organic pollutants,causing severe damage to the ecological environment.In this work,β-cyclodextrin carbon-sphere-based nanocompos-ite (CS/SiO2@β-CD) with a core-shell-shell configuration was prepared by hydrothermal synthesis and subsequent sedimentation-azeotropic distillation with SiO2 as intermediate layer for the removal of crystal violet (CV) and bisphenol A (BPA).The chemical structure and morphology of the CS/SiO2@β-CD were characterized by FT-IR,SEM and TEM.The effects of contact time,pH,temperature and initial concentration of the absorbates on the adsorption property were explored.The CS/SiO2@β-CD showed excellent adsorption capacity on CV and BPA,and the maximum adsorption capacity was 87.873 mg g-1 and 165.095 mg g-1,respectively.Their adsorption process was in line with the pseudo-second-order and pseudo-first-order kinetic models,respectively.The adsorption thermodynamics could be better fit-ted by Langmuir model than by Freundlich model.The calculated thermodynamic parameters (-△G0,△S0 and △H0) illustrated the adsorption of CV was endothermic,in contrast,the adsorption of BPA was exothermic process.Furthermore,the CS/SiO2@β-CD showed excellent recovery performance,making it a potential adsorbent for the practical treatment of textile wastewater.
文献关键词:
中图分类号:
作者姓名:
Tian Tian;Mengling Liu;Yinhui Li;Jian Han;Liang Ren;Heike Lorenz;Qing Wu;Jianxin Chen
作者机构:
School of Chemical Engineering and Technology,Hebei University of Technology,Tianjin 300130,China;MDPI (Tianjin) Technology Services Co.,Ltd.,Tianjin 300130,China;Max-Planck-Institut für Dynamik komplexer technischer Systeme,Sandtorstrasse 1,39106 Magdeburg,Germany;School of Artificial Intelligence,Hebei University of Technology,Tianjin 300130,China
文献出处:
引用格式:
[1]Tian Tian;Mengling Liu;Yinhui Li;Jian Han;Liang Ren;Heike Lorenz;Qing Wu;Jianxin Chen-.β-Cyclodextrin carbon-based nanoparticles with a core-shell-shell structure for efficient adsorption of crystal violet and bisphenol A)[J].颗粒学报(英文版),2022(03):88-97
A类:
nondegradable,azeotropic,absorbates
B类:
Cyclodextrin,carbon,nanoparticles,core,shell,structure,efficient,adsorption,crystal,violet,bisphenol,Textile,wastewater,contains,highly,toxic,carcinogenic,organic,pollutants,causing,severe,damage,ecological,environment,In,this,work,cyclodextrin,sphere,nanocompos,ite,CS,SiO2,CD,configuration,prepared,by,hydrothermal,synthesis,subsequent,sedimentation,distillation,intermediate,layer,removal,CV,BPA,chemical,morphology,were,characterized,FT,TEM,effects,contact,temperature,initial,concentration,property,explored,showed,excellent,capacity,maximum,respectively,Their,process,line,pseudo,second,order,first,kinetic,models,thermodynamics,could,better,fit,Langmuir,than,Freundlich,calculated,parameters,G0,S0,H0,illustrated,endothermic,contrast,exothermic,Furthermore,recovery,performance,making,potential,adsorbent,practical,treatment,textile
AB值:
0.560413
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