典型文献
Non-layer-transformed Mn3O4 cathode unlocks optimal aqueous magnesium-ion storage via synergizing amorphous ion channels and grain refinement
文献摘要：
Aqueous rechargeable magnesium ion batteries(ARMBs)have obtained more attention due to the two-electrons transfer nature,low cost and safety.However,the scarcity of cathode materials seriously hin-ders the development of ARMBs because of the unfavorable strong interaction between Mg2+and cathode material.Herein,we choose a pre-treated spinel Mn3O4 cathode for aqueous Mg2+storage.The pre-treatment in Na2SO4 solution induces the grain refinement decorated with tortuous amorphous ion dif-fusion channels,facilitating the production of electrochemical reaction active sites and the diffusion of Mg2+,respectively,which achieve a(sub-)surface pseudocapacitance reaction between Mn(Ⅱ)and Mn(Ⅲ).As a result,the pre-treated Mn3O4 cathode exhibits a package of optimal performances,i.e.,a capac-ity of 98.9 mAh g-1 and a high capacity retention rate of 99.4％after 2000 cycles.To the best of our knowl-edge,our work not only provides a new reaction mechanism of spinel Mn3O4 in aqueous batteries system,but also affords a high cycle stability electrode material for rechargeable Mg2+energy storage.
文献关键词：
中图分类号：
作者姓名：
Zhongyu Pan;Tingting Qin;Wei Zhang;Xianyu Chu;Taowen Dong;Nailin Yue;Zizhun Wang;Weitao Zheng
作者机构：
State Key Laboratory of Automotive Simulation and Control,School of Materials Science&Engineering,Key Laboratory of Mobile Materials MOE,Electron Microscopy Center,and International Center of Future Science,Jilin University,Changchun 130012,Jilin,China
文献出处：
引用格式：
[1]Zhongyu Pan;Tingting Qin;Wei Zhang;Xianyu Chu;Taowen Dong;Nailin Yue;Zizhun Wang;Weitao Zheng-.Non-layer-transformed Mn3O4 cathode unlocks optimal aqueous magnesium-ion storage via synergizing amorphous ion channels and grain refinement)[J].能源化学,2022(05):42-48
A类：
ARMBs,Mg2+storage,Mg2+energy
B类：
Non,layer,transformed,Mn3O4,cathode,unlocks,optimal,aqueous,magnesium,via,synergizing,amorphous,channels,grain,refinement,Aqueous,rechargeable,batteries,have,obtained,more,attention,due,two,electrons,transfer,nature,low,cost,safety,However,scarcity,materials,seriously,hin,ders,development,because,unfavorable,strong,interaction,between,Mg2+and,Herein,choose,pre,treated,spinel,treatment,Na2SO4,solution,induces,decorated,tortuous,facilitating,production,electrochemical,reaction,active,sites,diffusion,respectively,which,achieve,sub,surface,pseudocapacitance,result,exhibits,package,performances,mAh,high,capacity,retention,after,cycles,To,best,our,knowl,edge,work,not,only,provides,new,mechanism,system,but,also,affords,stability,electrode
AB值：
0.592029
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