典型文献
N-doped graphene anchored ultrasmall Ir nanoparticles as bifunctional electrocatalyst for overall water splitting
文献摘要:
Seeking for extremely active and durable bifunctional electrocatalysts towards the overall water splitting possesses a strategic significance on the development of sustainable and clean energy for the replacement of fossil fuels.Ir-based nanomaterials are deemed as one of the most high-efficiency oxygen evolution reaction electrocatalysts while the hydrogen evolution reaction performance is unfavorable.In this work,we report a one-pot hydrothermal synthesis of N-doped graphene anchored Ir nanoparticles(Ir/N-rGO)with ultrasmall particle size(~2.0 nm).Apart from the predictably superior OER performance,the resultant Ir/N-rGO also displays excellent hydrogen evolution reaction(HER)performance,requiring merely 76 and 260 mV overpotentials to achieve the current density of 10 mA cm-2 towards HER and OER,respectively.When applied as the bifunctional electrodes for overall water splitting,Ir/N-rGO needs a lower overpotential(1.74 V)to achieve a current density of 50 mA cm-2 in alkaline solution,exceeding that of Pt/C and RuO2 couple(1.85 V).Thus,the as-fabricated Ir/N-rGO has a commendable prospect in the practical application of alkaline water electrocatalysis.
文献关键词:
中图分类号:
作者姓名:
Wenqing Yao;Xian Jiang;Yulian Li;Cuiting Zhao;Linfei Ding;Dongmei Sun;Yawen Tang
作者机构:
Jiangsu Key Laboratory of New Power Batteries,Jiangsu Collaborative Innovation Center of Biomedical Functional Materials,School of Chemistry and Materials Science,Nanjing Normal University,Nanjing,210023,China;Advanced Analysis&Testing Center,Nanjing Forestry University,Nanjing,210037,China
文献出处:
引用格式:
[1]Wenqing Yao;Xian Jiang;Yulian Li;Cuiting Zhao;Linfei Ding;Dongmei Sun;Yawen Tang-.N-doped graphene anchored ultrasmall Ir nanoparticles as bifunctional electrocatalyst for overall water splitting)[J].绿色能源与环境(英文),2022(05):1111-1118
A类:
predictably
B类:
doped,graphene,anchored,ultrasmall,Ir,nanoparticles,bifunctional,overall,water,splitting,Seeking,extremely,active,durable,electrocatalysts,towards,possesses,strategic,significance,development,sustainable,clean,energy,replacement,fossil,fuels,nanomaterials,are,deemed,one,most,high,efficiency,oxygen,evolution,reaction,while,hydrogen,performance,unfavorable,In,this,work,report,hydrothermal,synthesis,rGO,size,Apart,from,superior,OER,resultant,also,displays,excellent,HER,requiring,merely,mV,overpotentials,achieve,current,density,mA,respectively,When,applied,electrodes,needs,lower,alkaline,solution,exceeding,that,Pt,RuO2,couple,Thus,fabricated,has,commendable,prospect,practical,application,electrocatalysis
AB值:
0.564238
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