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典型文献
Upconversion fluorescence modulation of CaTiO3∶ Yb3+/Er3+nanocubes via Zn2+introduction
文献摘要:
To investigate the effect of Zn2+ions on the luminescence properties of rare earth(RE)doped calcium titanate mate-rials,CaTiO3∶Yb3+/Er3+/Zn2+nanocubes with uniform size were prepared by solvothermal method in this paper.They were respectively characterized by X-ray diffractometer(XRD),scanning electron microscope(SEM),photolumines-cence(PL)spectroscopy and their fluorescence lifetimes.The results show that the average size of the nanocubes is about 550 nm×650 nm×850 nm with good upconversion luminescence(UCL)properties.Under 980 nm laser excita-tion,the effects of the ratio between activator Er3+and sensitizer Yb3+and Zn2+doping on the upconversion fluores-cence properties were investigated,and the optimal ion ratio was obtained.The results of steady-state spectra show that the strongest fluorescence intensity of CaTiO3∶Yb3+/Er3+was obtained with the addition of 10 mol%Zn2+at a Yb3+/Er3+molar doping ratio of 3∶0.3,which was attributed to the crystal field asymmetry generated by the introduc-tion of Zn2+ions.The energy transfer and upconversion mechanism between Yb3+and Er3+ions in CaTiO3 nanocubes were investigated by analyzing the upconversion fluorescence kinetics.
文献关键词:
作者姓名:
MU Jiajia;LIU Jinyu;GAO Lili
作者机构:
School of Science,Beihua University,Jilin 132013,China
引用格式:
[1]MU Jiajia;LIU Jinyu;GAO Lili-.Upconversion fluorescence modulation of CaTiO3∶ Yb3+/Er3+nanocubes via Zn2+introduction)[J].光电子快报(英文版),2022(03):129-134
A类:
Er3+nanocubes,Zn2+introduction,Zn2+nanocubes,photolumines,Er3+and,Zn2+doping,Er3+was,Zn2+at,Er3+molar
B类:
Upconversion,fluorescence,modulation,CaTiO3,via,To,Zn2+ions,luminescence,properties,rare,earth,RE,doped,calcium,titanate,mate,rials,uniform,size,were,prepared,by,solvothermal,method,this,paper,They,respectively,characterized,ray,diffractometer,scanning,electron,microscope,PL,spectroscopy,their,lifetimes,results,show,that,average,about,good,upconversion,UCL,Under,laser,excita,effects,ratio,between,activator,sensitizer,Yb3+and,investigated,optimal,obtained,steady,state,spectra,strongest,intensity,addition,which,attributed,crystal,field,asymmetry,generated,energy,transfer,mechanism,Er3+ions,analyzing,kinetics
AB值:
0.461547
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