典型文献
A Robust Heterometallic Cd(Ⅱ)/Ba(Ⅱ)-Organic Framework with Exposed Amino Group and Active Sites Exhibiting Excellent CO2/CH4 and C2H2/CH4 Separation
文献摘要：
A microporous and robust bimetal-organic framework[Cd2Ba(NH2-BTB)2]·2(DMA)·2(H2O)(1)was constructed by mixing the heterometallic nodes and an tridentate carboxyl ligand with amino group,benefiting from the synergistic effect of active sites,exposed amino groups and ultramicroporous structure.This compound displays an extraordinary selectivity of CO2/CH4 and C2H2/CH4(16.7 and 146.3)at 298 K and 1 atm,which can exceed those of many reported MOFs under the same conditions.This work provides an important model to design metal-organic frameworks for the adsorption and separation of small gas molecules.
文献关键词：
中图分类号：
作者姓名：
FU Hong-Ru;JIANG Yu-Ying;LUO Jia-Hua;LI Ting
作者机构：
College of Chemistry and Chemical Engineering,Luoyang Normal University,Luoyang 471934,China;College of Materials and Chemical Engineering,China Three Gorges University,Yichang 443002,China
文献出处：
引用格式：
[1]FU Hong-Ru;JIANG Yu-Ying;LUO Jia-Hua;LI Ting-.A Robust Heterometallic Cd(Ⅱ)/Ba(Ⅱ)-Organic Framework with Exposed Amino Group and Active Sites Exhibiting Excellent CO2/CH4 and C2H2/CH4 Separation)[J].结构化学,2022(03):287-292
A类：
Heterometallic,Exhibiting,Cd2Ba,heterometallic
B类：
Robust,Organic,Framework,Exposed,Amino,Group,Active,Sites,Excellent,CH4,C2H2,Separation,robust,bimetal,organic,NH2,BTB,DMA,H2O,was,constructed,by,mixing,nodes,tridentate,carboxyl,ligand,amino,benefiting,from,synergistic,effect,active,sites,exposed,groups,ultramicroporous,structure,This,compound,displays,extraordinary,selectivity,atm,which,can,exceed,those,many,reported,MOFs,under,same,conditions,provides,important,model,design,frameworks,adsorption,separation,small,gas,molecules
AB值：
0.672209
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
