典型文献
Manganese(Ⅱ)and Copper(Ⅰ)Compounds Based on Two Derivatives of Imidazo[1,5-a]pyridine:Synthesis,Structures,Magnetic Properties,and Catalytic Activity
文献摘要：
The utilization of 2,6-bis(imidazo[1,5-a]pyridin-3-yl)pyridine(bipp)and 3-(pyridin-2-yl)imidazo[l,5-a]pyridine(pip)in the compounds of manganese(Ⅱ)and copper(Ⅰ)ions is presented.Two complexes,[Mn(bipp)(SO4)(H2O)]n(1)and[Cu(pip)2]ClO4(2),were prepared with different characteristics in structure.Compound 1 exhibits a one-dimensional chain topology,and 2 is a homoleptic Cu(Ⅰ)complex.The dc magnetic susceptibility investigations reveal the antiferromagnetic(AF)MnⅡ…MnⅡ interactions in complex 1.The catalytic activity of compound 2 toward ketalization reactions was studied.Complex 2 exhibits high activity for the ketalization transformations of aliphatic ketones.
文献关键词：
中图分类号：
作者姓名：
ZHANG Qian;CUI Yan-Feng;ZHANG Xia-Mei;LI Ya-Hong;YAO Jin-Lei
作者机构：
College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou 215123,China;Jiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application,School of Physical Science and Technology,Suzhou University of Science and Technology,Suzhou 215009,China
文献出处：
引用格式：
[1]ZHANG Qian;CUI Yan-Feng;ZHANG Xia-Mei;LI Ya-Hong;YAO Jin-Lei-.Manganese(Ⅱ)and Copper(Ⅰ)Compounds Based on Two Derivatives of Imidazo[1,5-a]pyridine:Synthesis,Structures,Magnetic Properties,and Catalytic Activity)[J].结构化学,2022(03):148-154
A类：
bipp,pip,homoleptic,ketalization
B类：
Manganese,Copper,Compounds,Based,Two,Derivatives,Imidazo,pyridine,Synthesis,Structures,Magnetic,Properties,Catalytic,Activity,utilization,bis,imidazo,yl,compounds,manganese,copper,presented,complexes,Mn,SO4,H2O,ClO4,were,prepared,different,characteristics,structure,exhibits,dimensional,chain,topology,dc,susceptibility,investigations,reveal,antiferromagnetic,AF,interactions,catalytic,activity,toward,reactions,was,studied,Complex,high,transformations,aliphatic,ketones
AB值：
0.569307
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