典型文献
Catalytic Oxidation of Toluene over Nanorod Manganese Oxides Catalysts: Phase Change Effects
文献摘要：
Four manganese oxide (MnOx) catalysts with different phases were prepared via a hydrothermal method, and the toluene oxidation over the four manganese dioxide (MnOx) catalysts was studied. Among the catalysts, δ-MnO2 exhibits the best performance, excellent stability, and reusability. Moreover, δ-MnO2 possesses the highest specific surface area, with more exposed active sites compared to the other catalysts with which to make contact with toluene, leading to it exhibiting excellent activity. Furthermore, δ-MnO2 shows more lattice defects, Mn3+/(Mn3+ + Mn4+), oxygen vacancies, and surface adsorbed oxygen than the other catalysts, resulting in its excellent redox properties and catalytic performance. In addition, oxygen molecules adsorb on the oxygen vacancies of δ-MnO2, which are beneficial to the adsorption and oxidation of toluene, with benzyl alcohol, benzaldehyde, benzoic acid, and benzoic acid ester detected as specific intermediate products.
文献关键词：
中图分类号：
作者姓名：
Zhang Xuejun;Zhang Zhuofu;Song Zhongxian;Wu Yinghan;Liu Wei;Liu Zepeng;Liu Chunyu;Zhu Xinfeng
作者机构：
College of Environmental and Safety Engineering,Shenyang University of Chemical Technology,Shenyang 110142;Faculty of Environmental and Municipal Engineering,Henan Key Laboratory of Water Pollution Control and Rehabilitation Technology,Pingdingshan Key Laboratory of Carbon Emission Reduction and Complex Air Pollution Control Technology,Henan University of Urban Construction,Pingdingshan 467036
文献出处：
引用格式：
[1]Zhang Xuejun;Zhang Zhuofu;Song Zhongxian;Wu Yinghan;Liu Wei;Liu Zepeng;Liu Chunyu;Zhu Xinfeng-.Catalytic Oxidation of Toluene over Nanorod Manganese Oxides Catalysts: Phase Change Effects)[J].中国炼油与石油化工（英文版）,2022(03):67-76
A类：
Toluene
B类：
Catalytic,Oxidation,Nanorod,Manganese,Oxides,Catalysts,Phase,Change,Effects,Four,manganese,MnOx,catalysts,different,phases,were,prepared,via,hydrothermal,method,toluene,oxidation,four,dioxide,was,studied,Among,MnO2,exhibits,best,performance,excellent,stability,reusability,Moreover,possesses,highest,specific,surface,area,exposed,active,sites,compared,which,make,contact,leading,exhibiting,activity,Furthermore,shows,lattice,defects,Mn3+,Mn4+,oxygen,vacancies,adsorbed,than,resulting,redox,properties,catalytic,In,addition,molecules,beneficial,adsorption,benzyl,alcohol,benzaldehyde,benzoic,acid,ester,detected,intermediate,products
AB值：
0.610727
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