典型文献
A Double Crown Hexakis[(Di-μ-benzylthio)Nickel]Cluster:Synthesis,Structure and Properties
文献摘要：
The double crown hexakis[(di-μ-benzylthio)nickel]cluster,[Ni6(SCH2C6H5)12]·C2H5OH,was obtained by reacting C6H5CH2SNa with[(CH3)2CHOCS2]2Ni in EtOH.The results of electrochemical studies show that[Ni6(SCH2C6H5)12]is a quasi-reversible process.The crystal structure of[Ni6(SCH2C6H5)12]·C2H5OH is composed of discrete[Ni6(SCH2C6H5)12]and C2H5OH solvent molecules.Each Ni atom is surrounded by four S atoms of the μ2-SCH2C6H5 ligands in a distorted square-planar structure.The C6H5CH2S-side chains are arranged in the axial and equatorial positions,alternately,concerning the pseudo-hexagonal axis of the molecule.Strong π-π and C-H…π effects form the supramolecular nano-channel along the a-axis in the crystal,which wraps the solvent ethanol molecules in it.In addition,a wall is formed along the b-and c-axes,so that the ethanol molecules can freely enter and leave along the a-axis.These effects result in the ability of the title compound to adsorb and desorb ethanol molecules.Thermogravimetric analysis and powder X-ray diffraction at different temperature are provided to demonstrate this point.
文献关键词：
中图分类号：
作者姓名：
LIU E;JIA Ai-Quan;ZHANG Qian-Feng;JIAN Fang-Fang
作者机构：
Institute of Molecular Engineering and Applied Chemistry,Anhui University of Technology,Ma'anshan,Anhui 243002,China;School of Chemical Engineering and Pharmaceutics,Henan University of Science and Technology,Luoyang 471000,China
文献出处：
引用格式：
[1]LIU E;JIA Ai-Quan;ZHANG Qian-Feng;JIAN Fang-Fang-.A Double Crown Hexakis[(Di-μ-benzylthio)Nickel]Cluster:Synthesis,Structure and Properties)[J].结构化学,2022(03):40-46
A类：
Hexakis,benzylthio,hexakis,Ni6,SCH2C6H5,C6H5CH2SNa,2CHOCS2,C6H5CH2S,wraps
B类：
Double,Crown,Di,Nickel,Cluster,Synthesis,Structure,Properties,double,crown,nickel,cluster,C2H5OH,was,obtained,by,reacting,CH3,2Ni,EtOH,results,electrochemical,studies,show,that,quasi,reversible,process,crystal,structure,composed,discrete,solvent,molecules,Each,surrounded,four,atoms,ligands,distorted,square,planar,side,chains,arranged,axial,equatorial,positions,alternately,concerning,pseudo,hexagonal,axis,Strong,effects,supramolecular,nano,channel,along,which,ethanol,In,addition,wall,formed,axes,can,freely,enter,leave,These,ability,title,compound,adsorb,desorb,Thermogravimetric,analysis,powder,ray,diffraction,different,temperature,provided,demonstrate,this,point
AB值：
0.53526
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