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典型文献
Coordination Assembly of Tetrahedral Ti4(embonate)6 Cages with Alkaline-Earth Metal Ions
文献摘要:
Recently,the tetrahedral Ti4L6 cage (L =embonate) has been applied as the starting material to realize coordination assembly with transition and rare-earth ornoble metal ions through a two-step reaction.In this work,by employing the Ti4L6 cages to assemble with alkaline-earth metal ions (such as Mg2+,Ca2+ and Ba2+) under different solvothermal conditions,a series of Ti4L6-based structures from simple cages to 1D chain,2D layer and 3D framework have been synthesized and structurally characterized.In addition,thermal stability,phase purity,UV-vis absorption spectrum,the fluorescent and third-order nonlinear-optical properties are also investigated.
文献关键词:
作者姓名:
Ruiyan Chen;Guanghui Chen;Yanping He;Jian Zhang
作者机构:
College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350007,China;State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China
文献出处:
引用格式:
[1]Ruiyan Chen;Guanghui Chen;Yanping He;Jian Zhang-.Coordination Assembly of Tetrahedral Ti4(embonate)6 Cages with Alkaline-Earth Metal Ions)[J].结构化学,2022(01):1-6
A类:
embonate,Cages,Ti4L6,ornoble
B类:
Coordination,Assembly,Tetrahedral,Alkaline,Earth,Metal,Ions,Recently,tetrahedral,been,applied,starting,material,realize,coordination,assembly,transition,rare,earth,metal,through,two,step,reaction,In,this,by,employing,cages,assemble,alkaline,such,Mg2+,Ca2+,Ba2+,under,different,solvothermal,conditions,series,structures,from,simple,1D,chain,2D,layer,framework,have,synthesized,structurally,characterized,addition,stability,phase,purity,UV,vis,absorption,spectrum,fluorescent,third,order,nonlinear,optical,properties,also,investigated
AB值:
0.635368
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