典型文献
Cathayanalactone G and other constituents from leaves and twigs of Callicarpa cathayana
文献摘要:
Objective:To study the chemical constituents from the leaves and twigs of Callicarpa cathayana.Methods:The chemical constituents were isolated and purified by column chromatography on silica gel,MCI gel CHP 20P/P120,Sephadex LH-20,and HPLC.The structures of the compounds were determined by HR-ESI-MS,1D and 2D NMR data.Results:A total of 24 compounds were isolated from the 85%methanol extract of leaves and twigs of C.cathayana.They were identified as cathayanalactone G(1),a new diterpene,and 23 known compounds as patagonic acid(2),(-)-16-hydroxycledroda-3,13-dien-16,15-olide-18-oic acid(3),15-methoxypatagonic acid(4),oleanolic acid(5),ursolic acid(6),siaresinolic acid(7),pomolic acid(8),α-amyrin(9),tormentic acid(10),lupeol(11),5,7-dihydroxy-3,4'-dimethoxyflavone(12),5,4'-dihydroxy-3,7,3'-dimethoxyfla-vone(13),5-hydroxy-3,6,7,4'-tetramethoxyflavone(14),salvigenin(15),kaemferol(16),astragalin(17),pinoresinol 4-O-β-D-glucopyranoside(18),paulownin(19),β-sitosterol(20),β-sitosterol β-D-glucopyranoside(21),5-hydroxy-coumarin(22),isocopoletin(23),and 4-hydroxycinnamic acid(24).Conclusion:Compound 1 is a new labdane diterpene.Compounds 10,13,16 and 17 are isolated from the genus Callicarpa for the first time.Compounds 7,8,9,12,14,23 and 24 are reported from C.cathayana for the first time.
文献关键词:
中图分类号:
作者姓名:
Shuang Gong;Bin Cheng;Tiantian Sun;Xiaoli Li;Xinxin Liang;Yuan Wang;Xiaochang Dai;Weilie Xiao
作者机构:
Key Laboratory of Medicinal Chemistry for Natural Resource,Ministry of Education,Yunnan Research&Development Center for Natural Products,School of Chemical Science and Technology,Yunnan University,Kunming 650091,China
文献出处:
引用格式:
[1]Shuang Gong;Bin Cheng;Tiantian Sun;Xiaoli Li;Xinxin Liang;Yuan Wang;Xiaochang Dai;Weilie Xiao-.Cathayanalactone G and other constituents from leaves and twigs of Callicarpa cathayana)[J].中草药(英文版),2022(02):332-336
A类:
Cathayanalactone,cathayanalactone,patagonic,hydroxycledroda,methoxypatagonic,siaresinolic,amyrin,tormentic,dimethoxyflavone,dimethoxyfla,vone,tetramethoxyflavone,salvigenin,kaemferol,astragalin,paulownin,isocopoletin,labdane
B类:
other,constituents,from,leaves,twigs,Callicarpa,Objective,To,study,chemical,Methods,were,isolated,purified,by,column,chromatography,silica,gel,MCI,CHP,20P,P120,Sephadex,LH,HPLC,structures,compounds,determined,ESI,1D,2D,NMR,data,Results,total,methanol,extract,They,identified,new,diterpene,known,acid,dien,olide,oic,oleanolic,ursolic,pomolic,lupeol,dihydroxy,pinoresinol,glucopyranoside,sitosterol,coumarin,hydroxycinnamic,Conclusion,Compounds,genus,first,reported
AB值:
0.409921
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