典型文献
Enantioselectivity Tunable Gold-Catalyzed Intermolecular[3+2]Cycloaddition of N-Allenamides with Nitrones
文献摘要：
A highly enantioselective gold-catalyzed intermolecular[3+2]cycloaddition of N-allenamides with nitrones was realized by the application of Ming-Phos M6 as a chiral ligand.Both enantiomers of the cycloadducts with opposite configuration could be obtained in high yields with high regio-and enantioselectivity by the employment of either diastereomer of the chiral ligand.The acidic N—H bond(hydrogen bonding)of sulfinamide moiety of Ming-Phos and pentaflurophenyl substituent(fluorine effect)may play important roles in enhancement of enantioselectivity,that is,Ming-Phos is a multifunctional ligand in this transformation.
文献关键词：
中图分类号：
作者姓名：
Bing Xu;Zhan-Ming Zhang;Jie Han;Guangxin Gu;Junliang Zhang
作者机构：
Department of Chemistry,Fudan University,2005 Songhu Road,Shanghai 200438,China;Zhuhai Fudan Innovation Institute,Zhuhai,Guangdong 519000,China;Department of Materials Science,Fudan University,2005 Songhu Road,Shanghai 200438,China
文献出处：
引用格式：
[1]Bing Xu;Zhan-Ming Zhang;Jie Han;Guangxin Gu;Junliang Zhang-.Enantioselectivity Tunable Gold-Catalyzed Intermolecular[3+2]Cycloaddition of N-Allenamides with Nitrones)[J].中国化学（英文版）,2022(12):1407-1412
A类：
Enantioselectivity,Cycloaddition,Allenamides,Nitrones,allenamides,nitrones,cycloadducts,diastereomer,sulfinamide,pentaflurophenyl
B类：
Tunable,Gold,Catalyzed,Intermolecular,3+2,highly,enantioselective,gold,catalyzed,intermolecular,cycloaddition,was,realized,by,application,Ming,Phos,M6,chiral,ligand,Both,enantiomers,opposite,configuration,could,be,obtained,yields,regio,enantioselectivity,employment,either,acidic,hydrogen,bonding,moiety,substituent,fluorine,effect,may,play,important,roles,enhancement,that,multifunctional,this,transformation
AB值：
0.538782
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