典型文献
Asymmetric Transfer Hydrogenation of Diaryl Ketones with Ethanol Catalyzed by Chiral NCP Pincer Iridium Complexes
文献摘要：
The use of a chiral(NCP)lr complex as the precatalyst allowed for the discovery of asymmetric transfer hydrogenation of diaryl ketones with ethanol as the hydrogen source and solvent.This reaction was applicable to various ortho-substituted diaryl keontes,affording benzhydrols in good yields and enantioselectivities.This protocol could be carried out in a gram scale under mild reaction conditions.The utility of the catalytic system was highlighted by the synthesis of the key precursor of(S)-neobenodine.
文献关键词：
中图分类号：
作者姓名：
Lu Qian;Xixia Tang;Yulei Wang;Guixia Liu;Zheng Huang
作者机构：
School of Chemistry and Material Sciences,Hangzhou Institute of Advanced Study,University of Chinese Academy of Sciences,1 Sub-lane Xiangshan,Hangzhou,Zhejiang 310024,China;The State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,University of Chinese Academy of Sci-ences,Chinese Academy of Sciences,345 Lingling Road,Shanghai 200032,China;School of Physical Science and Technology,Shanghai Tech University,100 Haike Road,Shanghai 201210,China;Chang-Kung Chuang Institute,East China Normal University,Shanghai 200062,China
文献出处：
引用格式：
[1]Lu Qian;Xixia Tang;Yulei Wang;Guixia Liu;Zheng Huang-.Asymmetric Transfer Hydrogenation of Diaryl Ketones with Ethanol Catalyzed by Chiral NCP Pincer Iridium Complexes)[J].中国化学（英文版）,2022(10):1131-1136
A类：
Diaryl,Pincer,lr,precatalyst,diaryl,keontes,benzhydrols,neobenodine
B类：
Asymmetric,Transfer,Hydrogenation,Ketones,Ethanol,Catalyzed,by,Chiral,NCP,Iridium,Complexes,use,chiral,complex,allowed,discovery,asymmetric,transfer,hydrogenation,ketones,ethanol,source,solvent,This,reaction,was,applicable,various,ortho,substituted,affording,good,yields,enantioselectivities,protocol,could,carried,out,gram,scale,under,mild,conditions,utility,catalytic,system,highlighted,synthesis,key,precursor
AB值：
0.613619
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
