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典型文献
Crystalline,Rheological and Mechanical Enhancement in PBAT/PPC/Silica Nanocomposites with Double Percolation Network
文献摘要:
Nanocomposites of blends of biodegradable poly(butylene adipate-co-terephthalate)(PBAT)and sustainable poly(propylene carbonate)(PPC)with nanosilica were prepared by melt compounding method.PBAT/PPC blend was partially miscible system with sea-island structure,and nanosilica particles were selectively dispersed in the continuous phase PBAT matrix to form the double percolation network.The introduction of nanosilica into PBAT/PPC blend reduced the size of dispersed PPC phase,promoted the crystallization of PBAT in the nanocomposites,and increased the storage modulus of the nanocomposites.The study of rheological behaviors indicated that the double percolation network was formed at the nanosilica loading of 5 wt%,as a result,the nanocomposites exhibited the solid-like viscoelastic behavior and their relaxation time was extended.With the increase of the nanosilica content,the PBAT/PPC/silica nanocomposites displayed increased Young's modulus and yield strength.
文献关键词:
作者姓名:
You-Mei Ma;Feng-Xiang Gao;Shu-Ling Zhang
作者机构:
College of Chemistry,Jilin University,Changchun 130012,China;Key Laboratory of Polymer Ecomaterials,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China
引用格式:
[1]You-Mei Ma;Feng-Xiang Gao;Shu-Ling Zhang-.Crystalline,Rheological and Mechanical Enhancement in PBAT/PPC/Silica Nanocomposites with Double Percolation Network)[J].高分子科学(英文版),2022(11):1482-1492
A类:
Percolation,miscible
B类:
Crystalline,Rheological,Mechanical,Enhancement,PBAT,PPC,Silica,Nanocomposites,Double,Network,blends,biodegradable,poly,butylene,adipate,terephthalate,sustainable,propylene,carbonate,nanosilica,were,prepared,by,melt,compounding,method,was,partially,system,sea,island,structure,particles,selectively,dispersed,continuous,phase,matrix,double,percolation,network,introduction,into,reduced,size,promoted,crystallization,nanocomposites,increased,storage,modulus,study,rheological,behaviors,indicated,that,formed,loading,wt,result,exhibited,solid,like,viscoelastic,their,relaxation,extended,With,content,displayed,Young,yield,strength
AB值:
0.543319
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