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典型文献
Hybrid Janus Nanotubes with Tunable Internal Pore Size Disassembled from Mesoporous Block Copolymer-based Hybrid Scaffolds
文献摘要:
The hybrid Janus nanomaterials have captured considerable attention since the asymmetric structure can combine the properties of each component and display synergistic applications.However,the precise design of the specific hybrid Janus nanostructures still remains a formidable challenge.Here,we for the first time report the fabrication of novel and highly uniform inorganic/organic hybrid Janus nanotubes via disassembling the mesoporous inorganic nanoparticles(NPs)/polystyrene-block-poly(4-vinylpyridine)(PS-b-P4VP)hybrid sheets,which are generated through the in situ reduction of functional metal precursors on the prepared PS-b-P4VP mesoporous scaffolds.More importantly,the internal pore size of the hybrid Janus nanotubes can be precisely tuned by readily controlling the swelling time of the PS-b-P4VP sheet-like assemblies in a selective solvent for P4VP domains,thus generating the particular inorganic/organic hybrid Janus nanotubes with adjustable inner diameter size.We believe that our finding will provide an efficient and universal route to fabricate the particular inorganic/organic hybrid nanotubes for hierarchical functional devices and nanomaterials.
文献关键词:
作者姓名:
Chang-Xu Liu;Li-Jie Duan;Nan Yan;Wei Jiang
作者机构:
State Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China;School of Chemistry and Life Science,Changchun University of Technology,Changchun 130012,China
引用格式:
[1]Chang-Xu Liu;Li-Jie Duan;Nan Yan;Wei Jiang-.Hybrid Janus Nanotubes with Tunable Internal Pore Size Disassembled from Mesoporous Block Copolymer-based Hybrid Scaffolds)[J].高分子科学(英文版),2022(10):1165-1172
A类:
Disassembled,vinylpyridine,P4VP
B类:
Hybrid,Janus,Nanotubes,Tunable,Internal,Pore,Size,from,Mesoporous,Block,Copolymer,Scaffolds,hybrid,nanomaterials,have,captured,considerable,attention,since,asymmetric,can,combine,properties,each,component,display,synergistic,applications,However,design,specific,nanostructures,still,remains,formidable,challenge,Here,first,report,fabrication,novel,highly,uniform,inorganic,nanotubes,via,disassembling,mesoporous,nanoparticles,NPs,polystyrene,block,PS,sheets,which,generated,through,situ,reduction,functional,metal,precursors,prepared,scaffolds,More,importantly,internal,pore,size,precisely,tuned,by,readily,controlling,swelling,like,assemblies,selective,solvent,domains,thus,generating,particular,adjustable,inner,diameter,We,believe,that,our,finding,will,provide,efficient,universal,route,fabricate,hierarchical,devices
AB值:
0.61612
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