典型文献
Self-catalytic pyrolysis thermodynamics of waste printed circuit boards with co-existing metals
文献摘要:
Waste printed circuit boards(WPCBs)are generated increasingly recent years with the rapid replacement of electric and electronic products.Pyrolysis is considered to be a potential environmentally-friendly technology for recovering organic and metal resources from WPCBs.Thermogravimetric analysis and kinetic analysis of WPCBs were carried out in this study.It showed that the co-existing metals(Cu,Fe,Ni)in WPCBs have positive self-catalytic influence during the pyrolysis process.To illustrate their catalytic effects,the apparent activation energy was calculated by differential model.Contributions of different reactions during catalytic pyrolysis process was studied and the mechanism function was obtained by ?esták-Berggren model.The results showed that Cu,Fe,Ni can promote the reaction progress and reduce the apparent activation energy.Among the three metals,Ni plays better catalytic role than Cu,then Fe.This work provides theoretical base for understanding the three metals'catalytic influence during the pyrolysis of non-metal powders in WPCBs.
文献关键词:
中图分类号:
作者姓名:
Shuyu Chen;Run Li;Yaqi Shen;Lu Zhan;Zhenming Xu
作者机构:
School of Environmental Science and Engineering,Shanghai Jiao Tong University,Shanghai 200240,China
文献出处:
引用格式:
[1]Shuyu Chen;Run Li;Yaqi Shen;Lu Zhan;Zhenming Xu-.Self-catalytic pyrolysis thermodynamics of waste printed circuit boards with co-existing metals)[J].环境科学与工程前沿,2022(11):105-110
A类:
WPCBs
B类:
Self,catalytic,pyrolysis,thermodynamics,waste,printed,circuit,boards,existing,metals,Waste,generated,increasingly,recent,years,rapid,replacement,electric,electronic,products,Pyrolysis,considered,potential,environmentally,friendly,technology,recovering,organic,resources,from,Thermogravimetric,analysis,kinetic,were,carried,out,this,study,It,showed,that,have,positive,self,influence,during,process,To,illustrate,their,effects,apparent,activation,energy,calculated,by,differential,model,Contributions,reactions,studied,mechanism,function,obtained,est,Berggren,results,can,promote,progress,reduce,Among,three,plays,better,role,than,then,This,work,provides,theoretical,base,understanding,powders
AB值:
0.553398
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