典型文献
Vanadium nitride nanoparticles embedded in carbon matrix with pseudocapacitive behavior for high performance lithium-ion capacitors
文献摘要:
Lithium-ion capacitors(LICs)have attracted wide attention due to their potential of achieving merits of high-power output as well as high energy density.How-ever,the key issue of kinetics mismatch between anode and cathode hinders the electrochemical performance of LICs.Therefore,a vanadium nitride composite with nanoparti-cles embedded in carbon matrix(VN-C)was prepared as an efficiently pseudocapacitive anode material with high electronic conductivity and fast Li-ion diffusion rate.The VN-C composites were synthesized through one-step ammonia heating treatment at different temperatures among which the sample annealed at 600℃exhibits high specific capacity(513 mAh·g-1 at 0.1 A·g-1),outstanding rate performance(~300 mAh·g-1 at 10 A·g-1),and excellent cyclic steadiness(negligible capacity decay over 2000 cycles)in half-cell devices.A high-performance lithium-ion capacitor device was also fabricated by using VN-C-600 as the anode and activated carbon as the cath-ode,delivering a maximum energy density of 112.6 Wh·kg-1 and an extreme power density of 10 kW·kg-1.
文献关键词:
中图分类号:
作者姓名:
Jin-Hui Zhang;Zi-Yang Chen;Tie-Zhu Xu;Liu-Feng Ai;Ying-Hong Xu;Xiao-Gang Zhang;Lai-Fa Shen
作者机构:
Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies,College of Material Science and Technology,Nanjing University of Aeronautics and Astronautics,Nanjing 210016,China
文献出处:
引用格式:
[1]Jin-Hui Zhang;Zi-Yang Chen;Tie-Zhu Xu;Liu-Feng Ai;Ying-Hong Xu;Xiao-Gang Zhang;Lai-Fa Shen-.Vanadium nitride nanoparticles embedded in carbon matrix with pseudocapacitive behavior for high performance lithium-ion capacitors)[J].稀有金属(英文版),2022(07):2460-2469
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B类:
Vanadium,nitride,nanoparticles,embedded,carbon,matrix,pseudocapacitive,behavior,high,performance,lithium,capacitors,Lithium,LICs,have,attracted,wide,attention,due,their,potential,achieving,merits,power,output,well,energy,density,How,ever,key,issue,kinetics,mismatch,between,anode,cathode,hinders,electrochemical,Therefore,vanadium,VN,was,prepared,efficiently,material,electronic,conductivity,fast,diffusion,rate,composites,were,synthesized,through,one,step,ammonia,heating,treatment,different,temperatures,among,which,sample,annealed,exhibits,specific,capacity,mAh,outstanding,excellent,cyclic,steadiness,negligible,decay,over,cycles,half,devices,also,fabricated,by,using,activated,delivering,maximum,Wh,extreme,kW
AB值:
0.594148
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