典型文献
Bifunctional Mn-doped CoSe2 nanonetworks electrode for hybrid alkali/acid electrolytic H2 generation and glycerol upgrading
文献摘要：
Electrolytic water splitting,as a promising route to hydrogen(H2)production,is still confronted with the sluggish anodic oxygen evolution reaction(OER)and its less value-added O2 production.Herein,we report a bifunctional electrode fabricated by in situ growth of Mn-doped CoSe2 nanonetworks on carbon fiber cloth(Mn-CoSe2/CFC),which shows attractive electrocatalytic properties toward glycerol oxidation reaction(GOR)in alkali and hydrogen evolution reaction(HER)in acid.A flow alkali/acid hybrid elec-trolytic cell(fA/A-hEC)was then developed by coupling anodic GOR with cathodic HER with the Mn-CoSe2/CFC bifunctional electrode.Such fA/A-hEC enables a rather low voltage of 0.54 V to achieve 10 mA cm-2,and maintain long-term electrolysis stability over 300-h operation at 100 mA cm-2 with Faraday efficiencies of over 99％for H2 and 90％for formate production.The designed bifunctional elec-trode in such innovative fA/A-hEC device provides insightful guidance for coupling energy-efficient hydrogen production with biomass upgradation.
文献关键词：
中图分类号：
作者姓名：
Linfeng Fan;Yaxin Ji;Genxiang Wang;Zhifang Zhang;Luocai Yi;Kai Chen;Xi Liu;Zhenhai Wen
作者机构：
CAS Key Laboratory of Design and Assembly of Functional Nanostructures,and Fujian Key Laboratory of Nanomaterials,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,Fujian,China;College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350007,Fujian,China;School of Chemistry and Chemical Engineering,Yulin University,Yulin 719000,Shaanxi,China;University of Chinese Academy of Science,Beijing 100049,China
文献出处：
引用格式：
[1]Linfeng Fan;Yaxin Ji;Genxiang Wang;Zhifang Zhang;Luocai Yi;Kai Chen;Xi Liu;Zhenhai Wen-.Bifunctional Mn-doped CoSe2 nanonetworks electrode for hybrid alkali/acid electrolytic H2 generation and glycerol upgrading)[J].能源化学,2022(09):424-431
A类：
nanonetworks,trolytic,hEC,upgradation
B类：
Bifunctional,Mn,doped,CoSe2,electrode,hybrid,alkali,acid,electrolytic,H2,generation,glycerol,upgrading,Electrolytic,water,splitting,promising,route,hydrogen,production,still,confronted,sluggish,anodic,oxygen,evolution,reaction,OER,its,less,value,added,O2,Herein,we,report,bifunctional,fabricated,by,situ,growth,carbon,fiber,cloth,CFC,which,shows,attractive,electrocatalytic,properties,toward,oxidation,GOR,HER,flow,cell,fA,was,then,developed,coupling,cathodic,Such,enables,rather,voltage,achieve,mA,maintain,long,term,electrolysis,stability,over,operation,Faraday,efficiencies,formate,designed,such,innovative,device,provides,insightful,guidance,energy,efficient,biomass
AB值：
0.553042
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