典型文献
Efficient acetylene/carbon dioxide separation with excellent dynamic capacity and low regeneration energy by anion-pillared hybrid materials
文献摘要：
Adsorptive separation of acetylene/carbon dioxide mixtures by porous materials is an important and challenging task due to their similar sizes and physical properties.Here,remarkable acetylene/carbon dioxide separation featuring a high dynamic breakthrough capacity for acetylene(4.3 mmol·g-1)as well as an ultralow acetylene regeneration energy(29.5 kJ·mol-1)was achieved with the novel TiF62--pillared material ZU-100(TIFSIX-bpy-Ni).Construction of a pore structure with abundant TiF62-anion sites and pores with appropriate sizes enabled formation of acetylene clusters through hydrogen bonds and intermolecular interactions,which afforded a high acetylene capacity(8.3 mmol·g)and high acetylene/carbon dioxide uptake ratio(1.9)at 298 K and 1 bar.Moreover,the NbO52-anion-pillared material ZU-61 investigated for separation of acetylene/carbon dioxide.In addition,breakthrough experiments were also conducted to further confirm the excellent dynamic acetylene/carbon dioxide separation performance of ZU-100.
文献关键词：
中图分类号：
作者姓名：
Yijian Li;Jianbo Hu;Jiyu Cui;Qingju Wang;Huabin Xing;Xili Cui
作者机构：
Zhejiang Key Laboratory of Smart Biomaterials,Key Laboratory of Biomass Chemical Engineering of Ministry of Education,College of Chemical and Biological Engineering,Zhejiang University,Hangzhou 310027,China;ZJU-Hangzhou Global Scientific and Technological Innovation Center,Hangzhou 311215,China
文献出处：
引用格式：
[1]Yijian Li;Jianbo Hu;Jiyu Cui;Qingju Wang;Huabin Xing;Xili Cui-.Efficient acetylene/carbon dioxide separation with excellent dynamic capacity and low regeneration energy by anion-pillared hybrid materials)[J].化学科学与工程前沿,2022(11):1616-1622
A类：
TiF62,TIFSIX,NbO52
B类：
Efficient,acetylene,carbon,dioxide,separation,excellent,dynamic,capacity,regeneration,energy,by,anion,pillared,hybrid,materials,Adsorptive,mixtures,porous,is,important,challenging,task,due,their,similar,sizes,physical,properties,Here,remarkable,featuring,high,breakthrough,well,ultralow,kJ,was,achieved,novel,ZU,bpy,Construction,structure,abundant,sites,pores,appropriate,enabled,formation,clusters,hydrogen,bonds,intermolecular,interactions,which,afforded,uptake,bar,Moreover,investigated,In,addition,experiments,were,also,conducted,further,confirm,performance
AB值：
0.476542
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