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典型文献
Uncover the mystery of interfacial interactions in immiscible composites by spectroscopic microscopy:A case study with W-Cu
文献摘要:
Characterizing immiscible metallic composites with electron microscopy and X-ray spectroscopy is the classic way of obtaining their structural and physical details.Nevertheless,such a combination lacks abil-ity to tell the interfacial interactions at grain boundaries.Here we demonstrate a novel strategy to un-cover the mystery of interfacial interactions in such systems by spectroscopic microscopy.The morpho-logical and spectral data of samples were simultaneously recorded and analyzed,which reveals critical information regarding interfacial electronic modes.Taking W-Cu as a model,we experimentally quanti-fied its connectivity and unambiguously identified conditional bonding between W and Cu.Further,we chemically reconstructed the specific W-Cu boundary that possessed the strongest interactions and inves-tigated its atomic structure.The mechanism of W-Cu bonding was proposed and verified by first-principle calculations.The above methodology holds great promise to serve as a universal approach in achieving in-depth understanding of immiscible composites.
文献关键词:
作者姓名:
Zhi Zhao;Fawei Tang;Chao Hou;Xintao Huang;Xiaoyan Song
作者机构:
Faculty of Materials and Manufacturing,Key Laboratory of Advanced Functional Materials,Education Ministry of China,Beijing University of Technology,Beijing 100124,China
引用格式:
[1]Zhi Zhao;Fawei Tang;Chao Hou;Xintao Huang;Xiaoyan Song-.Uncover the mystery of interfacial interactions in immiscible composites by spectroscopic microscopy:A case study with W-Cu)[J].材料科学技术(英文版),2022(31):106-115
A类:
Uncover
B类:
mystery,interfacial,interactions,immiscible,composites,by,spectroscopic,microscopy,case,study,Characterizing,metallic,ray,spectroscopy,classic,way,obtaining,their,structural,physical,details,Nevertheless,such,combination,lacks,abil,tell,grain,boundaries,Here,demonstrate,novel,strategy,systems,morpho,logical,spectral,data,samples,were,simultaneously,recorded,analyzed,which,reveals,critical,information,regarding,electronic,modes,Taking,model,experimentally,quanti,its,connectivity,unambiguously,identified,conditional,bonding,between,Further,chemically,reconstructed,specific,boundary,that,possessed,strongest,inves,tigated,atomic,structure,mechanism,was,proposed,verified,first,principle,calculations,above,methodology,holds,great,promise,serve,universal,approach,achieving,depth,understanding
AB值:
0.649556
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