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典型文献
CuInS2/TiO2 heterojunction with elevated photo-electrochemical performance for cathodic protection
文献摘要:
Semiconductor quantum dots with high quantum yield and photovoltaic conversion efficiency have ush-ered in a brilliant moment for constructing internal electric field heterojunctions for photogenerated ca-thodic protection applications.In this paper,TiO2 nanotubes grown vertically on the surface of titanium substrates were modified via a combination of conventional electrochemical oxidation and a one-step solvothermal pathway to sensitize with CuInS2 quantum dots.Compared with pure TiO2 photoelectrodes,the modification improves sunlight absorption efficiency and provides photoelectron cathodic protection to the 304 stainless steel(304 SS).Through 9 h solvothermal reaction,the CuInS2/TiO2 coupled with pro-tected 304 SS exhibited an excellent property when the simulated sunlight irradiation.Its mixed open circuit potential is negatively shifted to-0.99 V,at the mean time with a stable photocurrent density(118 μA cm-2).The results indicate that CuInS2 and TiO2 established a p-n heterojunction with well-matched energy level,which can effectively facilitate the carrier separation and retain the strong redox capbility of photo-induced electrons and holes.
文献关键词:
作者姓名:
Juan Liu;Ning Wang;Fuwei Zheng;Chuanxing Wang;Jing Wang;Baorong Hou;Qianyu Zhao;Yanli Ning;Yiteng Hu
作者机构:
College of Chemical Engineering,Qingdao University of Science and Technology,No.53 Zhengzhou Road,Qingdao 266042,China;CAS Key Laboratory of Marine Environmental Corrosion and Bio-Fouling,Institute of Oceanology,Chinese Academy of Sciences,No.7 Nanhai Road,Qingdao 266071,China;Pilot National Laboratory for Marine Science and Technology,Open Studio for Marine Corrosion and Protection,Qingdao 266237,China;Center for Ocean Mega-Science,Chinese Academy of Sciences,No.7 Nanhai Road,Qingdao 266071,China
引用格式:
[1]Juan Liu;Ning Wang;Fuwei Zheng;Chuanxing Wang;Jing Wang;Baorong Hou;Qianyu Zhao;Yanli Ning;Yiteng Hu-.CuInS2/TiO2 heterojunction with elevated photo-electrochemical performance for cathodic protection)[J].材料科学技术(英文版),2022(27):211-218
A类:
ush,thodic,capbility
B类:
CuInS2,TiO2,elevated,electrochemical,performance,cathodic,protection,Semiconductor,quantum,dots,high,yield,photovoltaic,conversion,efficiency,have,ered,brilliant,moment,constructing,internal,electric,field,heterojunctions,photogenerated,applications,this,paper,nanotubes,grown,vertically,surface,titanium,substrates,were,modified,via,combination,conventional,oxidation,one,step,solvothermal,pathway,sensitize,Compared,pure,photoelectrodes,modification,improves,sunlight,absorption,provides,photoelectron,stainless,steel,SS,Through,reaction,coupled,tected,exhibited,excellent,property,when,simulated,irradiation,Its,mixed,open,circuit,potential,negatively,shifted,mean,stable,photocurrent,density,results,indicate,that,established,well,matched,energy,level,which,can,effectively,facilitate,carrier,separation,retain,strong,redox,induced,electrons,holes
AB值:
0.656881
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