首站-论文投稿智能助手
典型文献
Interfacial engineering regulated by CeOx to boost efficiently alkaline overall water splitting and acidic hydrogen evolution reaction
文献摘要:
Development of a low-cost and durable bifunctional electrocatalyst with high catalytic activity by hy-bridizing rare earth metal and non-noble metal is of utmost significance.Herein,a bifunctional electrocat-alyst consisting of MoO2 and CeOx heterostructure is synthesized via interfacial engineering.Particularly,due to its unique hetero-interface with abundant oxygen vacancies,the MoO2-CeOx/NF is able to exhibit outstanding hydrogen evolution reaction(HER)performance with an overpotential of 26 mV at 10 mA cm-2,and a preferable oxygen evolution reaction(OER)overpotential of 272 mV at 100 mA cm-2 in 1 M KOH.The recorded HER and OER overpotentials of MoO2-CeOx/NF are clearly smaller than those of Pt/C(HER overpotential of 27 mV)and RuO2(OER overpotential of 393 mV)at the same current density.More importantly,MoO2-CeOx/NF can also exhibit good HER activity with an overpotential of 50 mV at 10 mA cm-2 in acidic media.Thus,it is expected that this work can offer a new approach in the realization of high-catalytic alkaline overall water splitting and acidic HER performance through the rational design of rare-earth metal and non-noble metal heterostructure.
文献关键词:
作者姓名:
Jian Chen;Zhen Hu;Yang Ou;Qinghua Zhang;Xiaopeng Qi;Lin Gu;Tongxiang Liang
作者机构:
College of Rare Earth,Jiangxi University of Science and Technology,Ganzhou 341000,China;Faculty of Materials Metallurgy and Chemistry,Jiangxi University of Science and Technology,Ganzhou 341000,China;Institute of Physics,Chinese Academy of Science,Beijing 100190,China
引用格式:
[1]Jian Chen;Zhen Hu;Yang Ou;Qinghua Zhang;Xiaopeng Qi;Lin Gu;Tongxiang Liang-.Interfacial engineering regulated by CeOx to boost efficiently alkaline overall water splitting and acidic hydrogen evolution reaction)[J].材料科学技术(英文版),2022(25):129-138
A类:
bridizing
B类:
Interfacial,engineering,regulated,by,CeOx,boost,efficiently,alkaline,overall,water,splitting,acidic,hydrogen,evolution,reaction,Development,low,cost,durable,bifunctional,electrocatalyst,high,catalytic,activity,rare,earth,metal,noble,utmost,significance,Herein,consisting,MoO2,heterostructure,synthesized,via,interfacial,Particularly,due,its,unique,interface,abundant,oxygen,vacancies,exhibit,outstanding,HER,performance,mV,mA,preferable,OER,KOH,recorded,overpotentials,clearly,smaller,than,those,Pt,RuO2,same,current,density,More,importantly,also,good,media,Thus,expected,that,this,work,offer,new,approach,realization,through,rational,design
AB值:
0.469871
相似文献
CoFe-LDH nanowire arrays on graphite felt:A high-performance oxygen evolution electrocatalyst in alkaline media
Biao Deng;Jie Liang;Luchao Yue;Tingshuai Li;Qian Liu;Yang Liu;Shuyan Gao;Abdulmohsen Ali Alshehri;Khalid Ahmed Alzahrani;Yonglan Luo;Xuping Sun-Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province,School of Chemistry and Chemical Engineering,China West Normal University,Nanchong 637002,China;Institute of Fundamental and Frontier Sciences,University of Electronic Science and Technology of China,Chengdu 610054,China;Institute for Advanced Study,Chengdu University,Chengdu 610106,China;School of Materials Science and Engineering,Henan Normal University,Xinxiang 453007,China;Chemistry Department,Faculty of Science,King Abdulaziz University,P.O.Box 80203,Jeddah 21589,Saudi Arabia
Interface-engineered MoS2/CoS/NF bifunctional catalysts for highly-efficient water electrolysis
Wenxia Chen;Xingwang Zhu;Rui Wang;Wei Wei;Meng Liu;Shuai Dong;Kostya Ken Ostrikov;Shuang-Quan Zang-School of Chemistry and Chemical Engineering,Henan Key Laboratory of Biomolecular Recognition and Sensing,Henan D&A Engineering Center of Advanced Battery Materials,Shangqiu Normal University,Shangqiu 476000,Henan,China;College of Environmental Science and Engineering,Yangzhou University,Yangzhou 225009,Jiangsu,China;Henan Key Laboratory of Crystalline Molecular Functional Materials,Henan International Joint Laboratory of Tumor Theranostical Cluster Materials,Green Catalysis Center and College of Chemistry,Zhengzhou University,Zhengzhou 450001,Henan,China;School of Chemistry and Physics and Centre for Materials Science,Queensland University of Technology(QUT),Brisbane,QLD 4000,Australia
机标中图分类号,由域田数据科技根据网络公开资料自动分析生成,仅供学习研究参考。