典型文献
Interfacial engineering regulated by CeOx to boost efficiently alkaline overall water splitting and acidic hydrogen evolution reaction
文献摘要:
Development of a low-cost and durable bifunctional electrocatalyst with high catalytic activity by hy-bridizing rare earth metal and non-noble metal is of utmost significance.Herein,a bifunctional electrocat-alyst consisting of MoO2 and CeOx heterostructure is synthesized via interfacial engineering.Particularly,due to its unique hetero-interface with abundant oxygen vacancies,the MoO2-CeOx/NF is able to exhibit outstanding hydrogen evolution reaction(HER)performance with an overpotential of 26 mV at 10 mA cm-2,and a preferable oxygen evolution reaction(OER)overpotential of 272 mV at 100 mA cm-2 in 1 M KOH.The recorded HER and OER overpotentials of MoO2-CeOx/NF are clearly smaller than those of Pt/C(HER overpotential of 27 mV)and RuO2(OER overpotential of 393 mV)at the same current density.More importantly,MoO2-CeOx/NF can also exhibit good HER activity with an overpotential of 50 mV at 10 mA cm-2 in acidic media.Thus,it is expected that this work can offer a new approach in the realization of high-catalytic alkaline overall water splitting and acidic HER performance through the rational design of rare-earth metal and non-noble metal heterostructure.
文献关键词:
中图分类号:
作者姓名:
Jian Chen;Zhen Hu;Yang Ou;Qinghua Zhang;Xiaopeng Qi;Lin Gu;Tongxiang Liang
作者机构:
College of Rare Earth,Jiangxi University of Science and Technology,Ganzhou 341000,China;Faculty of Materials Metallurgy and Chemistry,Jiangxi University of Science and Technology,Ganzhou 341000,China;Institute of Physics,Chinese Academy of Science,Beijing 100190,China
文献出处:
引用格式:
[1]Jian Chen;Zhen Hu;Yang Ou;Qinghua Zhang;Xiaopeng Qi;Lin Gu;Tongxiang Liang-.Interfacial engineering regulated by CeOx to boost efficiently alkaline overall water splitting and acidic hydrogen evolution reaction)[J].材料科学技术(英文版),2022(25):129-138
A类:
bridizing
B类:
Interfacial,engineering,regulated,by,CeOx,boost,efficiently,alkaline,overall,water,splitting,acidic,hydrogen,evolution,reaction,Development,low,cost,durable,bifunctional,electrocatalyst,high,catalytic,activity,rare,earth,metal,noble,utmost,significance,Herein,consisting,MoO2,heterostructure,synthesized,via,interfacial,Particularly,due,its,unique,interface,abundant,oxygen,vacancies,exhibit,outstanding,HER,performance,mV,mA,preferable,OER,KOH,recorded,overpotentials,clearly,smaller,than,those,Pt,RuO2,same,current,density,More,importantly,also,good,media,Thus,expected,that,this,work,offer,new,approach,realization,through,rational,design
AB值:
0.469871
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