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典型文献
Urea-assisted hydrothermal synthesis of MnMoO4/MnCO3 hybrid electrochemical electrode and fabrication of high-performance asymmetric supercapacitor
文献摘要:
Transition metal molybdates/carbonates and hybrid nanomaterials have attracted great attention in en-ergy storage applications because of their enriched redox activity,good electronic conductivity,and sta-ble crystallinity.We synthesize a multicomponent MnMoO4/MnCO3 hybrid by a one-step hydrothermal method with urea as the reaction fuel.By controlling only the urea concentration in the initial pre-cursor solution,the MnMoO4/MnCO3 molecular ratio is controlled effectively,which is found to have a profound effect on the electrochemical properties of the hybrid electrodes.The electrochemical mea-surements show that the specific capacitance of MnMoO4/MnCO3 hybrid is 1311 F/g,the energy density of 116.8 Wh/kg,and power density of 383 W/kg at a current density of 1 A/g with 79% capacitance re-tention over 5000 cycles.The fabricated asymmetric supercapacitor device exhibits good energy storage performance,including the specific capacitance of 97 F/g along with the energy density of 26.5 Wh/kg and the power density of 657 W/kg at a current density of 1 A/g and good reversibility with capaci-tance retention of 85% after 2000 cycles and 70% over 5000 cycles.The increase in the energy density of 900% with a mere 60% decrement in the energy density indicates its potential superior applications in high-power devices.
文献关键词:
作者姓名:
Mohan Reddy Pallavolu;Arghya Narayan Banerjee;Ramesh Reddy Nallapureddy;Sang W.Joo
作者机构:
School of Mechanical Engineering and Center for Research Facilities,Yeungnam University,Gyeongsan 38541,South Korea
引用格式:
[1]Mohan Reddy Pallavolu;Arghya Narayan Banerjee;Ramesh Reddy Nallapureddy;Sang W.Joo-.Urea-assisted hydrothermal synthesis of MnMoO4/MnCO3 hybrid electrochemical electrode and fabrication of high-performance asymmetric supercapacitor)[J].材料科学技术(英文版),2022(01):332-344
A类:
MnMoO4,molybdates
B类:
Urea,assisted,hydrothermal,synthesis,MnCO3,hybrid,electrochemical,fabrication,high,performance,asymmetric,supercapacitor,Transition,metal,carbonates,nanomaterials,have,attracted,great,attention,storage,applications,because,their,enriched,redox,activity,good,electronic,conductivity,ble,crystallinity,We,synthesize,multicomponent,by,step,method,urea,reaction,fuel,By,controlling,only,concentration,initial,pre,cursor,solution,molecular,controlled,effectively,which,profound,properties,electrodes,mea,surements,show,that,specific,capacitance,energy,density,Wh,power,current,over,cycles,fabricated,exhibits,including,along,reversibility,retention,after,increase,mere,decrement,indicates,potential,superior,devices
AB值:
0.481339
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