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典型文献
Converting furfural residue wastes to carbon materials for high performance supercapacitor
文献摘要:
Sustainable development based on the value-added utilization of furfural residues(FRs)is an effective way to achieve a profitable circular economy.This comprehensive work highlights the potential of FRs as precursor to prepare porous carbons for high performance supercapacitors(SCs).To improve the electrochemical performance of FR-based carbon materials,a facile route based on methanol pretreatment coupled with pre-carbonization and followed KOH activation is proposed.More defects could be obtained after methanol treatment,which is incline to optimize textural structure.The activated methanol treated FR-based carbon materials(AFRMs)possess high specific surface area(1753.5 m2 g-1),large pore volume(0.85 cm3 g-1),interconnected micro/mesoporous structure,which endow the AFRMs with good elec-trochemical performance in half-cell(326.1 F g-1 at 0.1 A g-1,189.4 F g-1 at 50 A g--1 in 6 mol L-1 KOH).The constructed symmetric SCs based on KOH,KOH-K3Fe(CN)6 and KOH-KI electrolyte deliver energy density up to 8.9,9.9 and 10.6 Wh kg-1 with a capacitance retention of over 86%after 10,000 cycles.Furthermore,the self-discharge can be restrained by the addition of K3Fe(CN)6 and KI in KOH electrolyte.This study provides an effective approach for high-valued utilization of FR waste.
文献关键词:
作者姓名:
Xiaoying Guo;Xusheng Zhang;Yingxiong Wang;Xiaodong Tian;Yan Qiao
作者机构:
State Key Laboratory of Coal Conversion,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan,030001,China;Center of Materials Science and Optoelectronics Engineering,University of Chinese Academy of Sciences,Beijing,100049,China;CAS Key Laboratory of Carbon Materials,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan,030001,China;Shanxi Engineering Research Center of Biorefinery,Institute of Coal Chemistry,Chinese Academy of Sciences,27 South Taoyuan Road,Taiyuan,030001,China
引用格式:
[1]Xiaoying Guo;Xusheng Zhang;Yingxiong Wang;Xiaodong Tian;Yan Qiao-.Converting furfural residue wastes to carbon materials for high performance supercapacitor)[J].绿色能源与环境(英文),2022(06):1270-1280
A类:
FRs,AFRMs
B类:
Converting,furfural,wastes,materials,performance,Sustainable,development,added,utilization,residues,effective,way,achieve,profitable,circular,economy,This,comprehensive,work,highlights,potential,precursor,prepare,carbons,supercapacitors,SCs,To,improve,electrochemical,facile,route,methanol,pretreatment,coupled,carbonization,followed,KOH,activation,proposed,More,defects,could,be,obtained,after,which,incline,optimize,textural,structure,activated,treated,possess,specific,surface,area,large,pore,volume,cm3,interconnected,micro,mesoporous,endow,good,half,cell,constructed,symmetric,K3Fe,CN,KI,electrolyte,deliver,energy,density,Wh,capacitance,retention,over,cycles,Furthermore,self,discharge,can,restrained,by,addition,study,provides,approach,valued
AB值:
0.548759
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