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典型文献
Preparation of Hydrophilic and Shrink-Proofing Wool Fabrics Through Thiol-Ene Click Chemistry Reaction
文献摘要:
To improve shrink-proofing performance and hydrophilicity of wool fabrics, the wool fibers were modified by poly (ethylene glycol) dimethacrylate (PEGDMA) through thiol-ene click chemistry reaction. Firstly, wool fabrics were reduced at room temperature with a high-efficiency disulfide bond reducing agent, tris ( 2-carbonxyethyl) phosphine hydrochloride (TCEP). Then the thiol-ene click chemistry reaction was initiated by dimethyl 2, 2'-azobis (2-methylpropionate) ( AIBME) through the heating method. Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, and scanning electron microscopy test results all showed that PEGDMA was successfully grafted onto wool fabric surface. Physical properties, hydrophilicity, and shrink-proofing performance were assessed. The wetting time of PEGDMA grafted wool fabrics decreased to about 3 s. After being grafted with PEGDMA, the felting shrinkage of wool fabrics rapidly decreased to about 8%. The anti-pilling properties of wool fabrics were also greatly improved to 5 class after 2000 times of friction. Meanwhile, the load retention rate of fabrics could reach 90%. It provides a method of wool modification to improve hydrophilicity and anti-felting performance.
文献关键词:
作者姓名:
WANG Litao;ZHOU Aihui;DAI Chenlu;YUAN Jiugang
作者机构:
Key Laboratory of Science&Technology of Eco-Textile,Ministry of Education,Jiangnan University,Wuxi 214122,China;Fujian Fiber Inspection Center,Fuzhou 350000,China
引用格式:
[1]WANG Litao;ZHOU Aihui;DAI Chenlu;YUAN Jiugang-.Preparation of Hydrophilic and Shrink-Proofing Wool Fabrics Through Thiol-Ene Click Chemistry Reaction)[J].东华大学学报(英文版),2022(05):426-434
A类:
Shrink,Proofing,Thiol,PEGDMA,carbonxyethyl,methylpropionate,AIBME,felting,pilling
B类:
Preparation,Hydrophilic,Wool,Fabrics,Through,Ene,Click,Chemistry,Reaction,To,proofing,performance,hydrophilicity,wool,fabrics,fibers,were,modified,by,poly,ethylene,glycol,dimethacrylate,through,thiol,click,chemistry,reaction,Firstly,reduced,room,temperature,high,efficiency,disulfide,bond,reducing,agent,tris,phosphine,hydrochloride,TCEP,Then,was,initiated,dimethyl,azobis,heating,method,Fourier,transform,infrared,FTIR,spectroscopy,Raman,scanning,electron,microscopy,test,results,all,showed,that,successfully,grafted,onto,surface,Physical,properties,assessed,wetting,decreased,about,After,being,shrinkage,rapidly,anti,also,greatly,improved,class,after,times,friction,Meanwhile,load,retention,rate,could,reach,It,provides,modification
AB值:
0.525048
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