典型文献
Iridium(I)-catalyzed deoxgenation of fluoroalkylsulfoxides with dimethyl diazomalonate to access fluoroalkylthioethers
文献摘要：
A new method for the preparation of fluoroalkylthioethers including trifluoromethylthioether and diflu-oromethylthioether by iridium(Ⅰ)-catalyzed deoxgenation of fluoroalkylsulfoxides with dimethyl diazoma-lonate was developed.In the reaction system,dimethyl diazomalonate was used as reducing reagent and the corresponding fluoroalkylthioethers were produced through oxygen atom transfer from fluoroalkylsul-foxides to diazomalonate.The protocol featuring effective oxygen atom transfer,mild reaction conditions and good functional groups tolerance offers an alternative strategy for the synthesis of fluoroalkylth-ioethers.
文献关键词：
中图分类号：
作者姓名：
Wenqing Lu;Wenlin Li;Yicheng Zhou;Yongbin Xie;Wenbo Chen
作者机构：
Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power,Shanghai University of Electric Power,Shanghai 200090,China;CAS Key Laboratory of Energy Regulation Materials,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China
文献出处：
引用格式：
[1]Wenqing Lu;Wenlin Li;Yicheng Zhou;Yongbin Xie;Wenbo Chen-.Iridium(I)-catalyzed deoxgenation of fluoroalkylsulfoxides with dimethyl diazomalonate to access fluoroalkylthioethers)[J].中国化学快报（英文版）,2022(11):4865-4869
A类：
deoxgenation,fluoroalkylsulfoxides,diazomalonate,fluoroalkylthioethers,trifluoromethylthioether,diflu,oromethylthioether,diazoma,lonate,fluoroalkylsul,foxides,fluoroalkylth,ioethers
B类：
Iridium,catalyzed,dimethyl,access,new,method,preparation,including,by,iridium,was,developed,In,reaction,system,used,reducing,reagent,corresponding,were,produced,through,oxygen,atom,transfer,from,protocol,featuring,effective,mild,conditions,good,functional,groups,tolerance,offers,alternative,strategy,synthesis
AB值：
0.391081
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
