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典型文献
A natural manganese ore as a heterogeneous catalyst to effectively activate peroxymonosulfate to oxidize organic pollutants
文献摘要:
Heterogeneous transition metal catalysts are indispensable in improving environmental pollution.How-ever,their fabrication is often costly and cumbersome,and they can easily pollute the environment.This study proposed using a natural Gabonese ore(GBO)containing MnxOy and FexOy as catalysts to degrade orange Ⅱ(OⅡ)via peroxymonosulfate(PMS)activation.The GBO+PMS system exhibited extraordinarily high stability and catalytic activity towards OⅡ elimination(92.2%,0.0453 min-1).The reactive oxygen species(ROS)generated in the system were identified using radical scavenging tests and electron spin-resonance(ESR)analysis.Singlet oxygen(1O2)represented the dominant reactive species for OⅡ degrada-tion,while the system presented a lower reaction energy barrier and was effective in a broad pH range(2-10).This work also proposed the activation mechanism for the GBO+PMS system and OⅡ degrada-tion pathways.This study revealed a new approach for exploring inexpensive,eco-friendly,efficient,and stable heterogeneous transition metal catalysts.
文献关键词:
作者姓名:
Jinchuan Gu;Ping Yin;Yi Chen;Honglin Zhu;Rui Wang
作者机构:
School of Food and Bioengineering,Civil Engineering and Architecture and Environment,Emergency Science,Xihua University,Chengdu 610039,China;Sichuan Rongxinkai Engineering Design Co.,Ltd.,Chengdu 610039,China;Faculty of Geosciences and Environmental Engineering,Southwest Jiaotong University,Chengdu 611756,China
引用格式:
[1]Jinchuan Gu;Ping Yin;Yi Chen;Honglin Zhu;Rui Wang-.A natural manganese ore as a heterogeneous catalyst to effectively activate peroxymonosulfate to oxidize organic pollutants)[J].中国化学快报(英文版),2022(11):4792-4797
A类:
GBO+PMS
B类:
natural,manganese,ore,heterogeneous,effectively,activate,peroxymonosulfate,oxidize,organic,pollutants,Heterogeneous,transition,metal,catalysts,are,indispensable,improving,environmental,pollution,How,ever,their,fabrication,often,costly,cumbersome,they,can,easily,pollute,This,study,proposed,using,Gabonese,containing,MnxOy,FexOy,degrade,orange,via,activation,system,exhibited,extraordinarily,high,stability,catalytic,activity,towards,elimination,reactive,oxygen,species,ROS,generated,were,identified,radical,scavenging,tests,electron,spin,resonance,ESR,analysis,Singlet,1O2,represented,dominant,degrada,while,lower,reaction,energy,barrier,was,broad,work,also,mechanism,pathways,revealed,new,approach,exploring,inexpensive,eco,friendly,efficient,stable
AB值:
0.66493
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