典型文献
A trefoil-shaped macrocycle with[12]-imidazolium cations
文献摘要：
A trefoil-like two-dimensional(2D)C3v symmetric organic[12]-imidazolium cation H12-2(PF6)12 featur-ing three[4]-imidazolium macrocycles was synthesized in three steps.The reaction of a dodecakis H12-1(PF6)12 imidazolium salt with Ag2O resulted in the formation of a hexanuclear Ag1 dodecacarbene as-sembly[Ag6(1)](PF6)6.Upon UV irradiation,the photodimerization of the cinnamic ester pendants of[Ag6(1)](PF6)6 led to the generation of a trefoil-like complex[Ag6(2)](PF6)6 containing three closed met-allacycles.Removal of metal ions allowed for the synthesis of the target molecule.All complexes were fully characterized by NMR spectroscopy(1H,13C{1H}and 2D NMR)and high-resolution electrospray ion-ization mass spectrometry(HR-ESI-MS).
文献关键词：
中图分类号：
作者姓名：
Le Zhang;Li-Ying Sun;Jin-Ping Chang;Hui-Yu Xie;Ya-Wen Zhang;Yi-Fan Zhang;Ying-Feng Han
作者机构：
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education,College of Chemistry and Materials Science,Northwest University,Xi'an 710127,China
文献出处：
引用格式：
[1]Le Zhang;Li-Ying Sun;Jin-Ping Chang;Hui-Yu Xie;Ya-Wen Zhang;Yi-Fan Zhang;Ying-Feng Han-.A trefoil-shaped macrocycle with[12]-imidazolium cations)[J].中国化学快报（英文版）,2022(10):4567-4571
A类：
macrocycle,featur,dodecakis,hexanuclear,dodecacarbene,Ag6,photodimerization,pendants,allacycles
B类：
trefoil,shaped,imidazolium,cations,like,two,dimensional,2D,C3v,symmetric,organic,H12,PF6,three,macrocycles,was,synthesized,steps,reaction,salt,Ag2O,resulted,formation,Ag1,sembly,Upon,UV,irradiation,cinnamic,ester,led,generation,containing,closed,Removal,metal,allowed,synthesis,target,molecule,All,complexes,were,fully,characterized,by,NMR,spectroscopy,1H,13C,high,resolution,electrospray,mass,spectrometry,ESI
AB值：
0.493959
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
