典型文献
Extending aromatic acids on TiO2 for cooperative photocatalysis with triethylamine:Violet light-induced selective aerobic oxidation of sulfides
文献摘要：
Designing visible light photocatalysts with a metal oxide semiconductor as the starting material could expand a new horizon for the conversion and storage of solar energy.Here,the benchmark photocatalyst TiO2 was used to pursue this goal by anchoring aromatic acids.Extending the aromatic acid was strate-gically deployed to design TiO2 complexes with violet light-induced selective aerobic oxidation of sulfide as the probe reaction.With benzoic acid(BA)as the initial molecule,horizontally extending one or two benzene rings furnishes 2-naphthoic acid(2-NA)and 2-anthracene acid(2-AA).Moreover,triethylamine(TEA),an electron transfer mediator,was introduced to maintain the integrity of the anchored aromatic acids.Notably,there was a direct correlation between the π-conjugation of aromatic acid ligand and the selective aerobic oxidation of sulfides.Among the three aromatic acids,2-AA delivered the best re-sult over TiO2 due to the most extensive π-conjugated system.Ultimately,violet light-induced selective aerobic oxidation of sulfides into corresponding sulfoxides was conveniently realized by cooperative pho-tocatalysis of 2-AA-TiO2 with 10 mol％of TEA.This work affords an extending strategy for designing the next-generation ligands for semiconductors to expand visible light-induced selective reactions.
文献关键词：
中图分类号：
作者姓名：
Hui Li;Xia Li;Jun Zhou;Wenlong Sheng;Xianjun Lang
作者机构：
Sauvage Center for Molecular Sciences,College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072,China
文献出处：
引用格式：
[1]Hui Li;Xia Li;Jun Zhou;Wenlong Sheng;Xianjun Lang-.Extending aromatic acids on TiO2 for cooperative photocatalysis with triethylamine:Violet light-induced selective aerobic oxidation of sulfides)[J].中国化学快报（英文版）,2022(08):3733-3738
A类：
triethylamine,gically,furnishes,naphthoic,sulfoxides,tocatalysis
B类：
Extending,aromatic,acids,TiO2,cooperative,photocatalysis,Violet,light,induced,selective,aerobic,oxidation,sulfides,Designing,visible,photocatalysts,metal,starting,material,could,expand,new,conversion,storage,solar,energy,Here,benchmark,was,used,pursue,this,goal,by,anchoring,deployed,complexes,violet,probe,With,benzoic,BA,initial,molecule,horizontally,extending,one,two,benzene,rings,NA,anthracene,AA,Moreover,TEA,electron,transfer,mediator,introduced,maintain,integrity,anchored,Notably,there,direct,correlation,between,conjugation,Among,three,delivered,best,sult,due,most,extensive,conjugated,system,Ultimately,into,corresponding,conveniently,realized,This,work,affords,strategy,designing,next,generation,ligands,semiconductors,reactions
AB值：
0.503551
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