典型文献
Circularly polarized luminescence based on cholesterol-tetraphenylethylene-perylene liquid crystal
文献摘要：
Perylene derivative with circularly polarized luminescence(CPL)at aggregated state was seldom re-ported due to the strong ACQ(aggregation-caused quench)effect at aggregation.In this work,a novel cholesterol-tetraphenylethylene-perylene derivative(TPE-P)was designed and synthesized in moderate yield.It exhibited liquid crystalline behavior with orderly hexagonal columnar mesophase and good flu-orescence emission at long wavelength(600-700 nm)not only in solution but also at aggregated states based on the AIE(aggregation-induced emission)-FRET(fluorescence resonance energy transfer)effect between tetraphenylethylene unit and perylene moiety.Moreover,the circular dichroism(CD)and CPL studies suggested the effective chiral transfer from cholesterol unit to tetraphenylethylene unit and pery-lene skeleton due to the spiral liquid crystalline self-assembly.The CD and CPL signals showed the order of THF＜THF-hexane＜solid film＜meosphase,indicating that the higher spiral orderly degree resulted in the stronger chiral transfer.The largest|glum|value for mesophase excited at 320 nm was as high as 1.5×10-2 based on the combining effect of AIE-FRET and chiral transfer.This research not only reported a novel CPL perylene derivative at aggregated state,but also confirmed that the combination of AIE-FRET effect and chiral transfer of liquid crytalline phase was an effective method to construct normal dye with excellent CPL property in aggregated state.
文献关键词：
中图分类号：
作者姓名：
Shengjie Jiang;Shujuan Zhou;Ying Chen;Hongyu Guo;Fafu Yang
作者机构：
College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350007,China;Fujian Key Laboratory of Polymer Materials,Fuzhou 350007,China;Fujian provincial Key Laboratory of Advanced Materials Oriented Chemical Engineering,Fuzhou 350007,China
文献出处：
引用格式：
[1]Shengjie Jiang;Shujuan Zhou;Ying Chen;Hongyu Guo;Fafu Yang-.Circularly polarized luminescence based on cholesterol-tetraphenylethylene-perylene liquid crystal)[J].中国化学快报（英文版）,2022(05):2442-2446
A类：
pery,meosphase,glum,crytalline
B类：
Circularly,polarized,luminescence,cholesterol,tetraphenylethylene,perylene,liquid,Perylene,derivative,circularly,CPL,aggregated,was,seldom,due,ACQ,aggregation,caused,quench,In,this,work,novel,TPE,designed,synthesized,moderate,yield,It,exhibited,crystalline,behavior,orderly,hexagonal,columnar,mesophase,good,emission,long,wavelength,not,only,solution,but,also,states,AIE,induced,FRET,fluorescence,resonance,energy,transfer,between,unit,moiety,Moreover,dichroism,CD,studies,suggested,effective,chiral,from,skeleton,spiral,self,assembly,signals,showed,THF,hexane,solid,film,indicating,that,higher,degree,resulted,stronger,largest,value,excited,combining,This,research,reported,confirmed,combination,method,construct,normal,dye,excellent,property
AB值：
0.459619
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