典型文献
Abnormal Elastic Changes for Cubic-Tetragonal Transition of Single-Crystal SrTiO3
文献摘要：
Strontium titanate(SrTiO3)is a typical perovskite-type ceramic oxide and studying its high-pressure phases are critical to understand the ferroelastic phase transition.SrTiO3 also can be used as an important analog of davemaoite(CaSiO3)to understand the compositional and velocity structure of the Earth's interior.However,the high-pressure studies on the cubic-to-tetragonal phase transition pressure and elastic properties remain unclear for SrTiO3.Here,we investigate the phase transition and elasticity of single-crystal SrTiO3 by Raman and Brillouin scattering combined with diamond anvil cell.The acoustic velocities of single-crystal SrTiO3 and the independent elastic constants of cubic and tetragonal SrTiO3 are determined up to 27.5 GPa at room temperature.This study indicates that C11,C12,and C44 exhibit abnormal changes at 10.3 GPa,which is related to the cubic-to-tetragonal phase transition.Interestingly,a significant softening on shear modulus and a large anisotropy of shear wave splitting(ASPO)jump are observed at 10.3 GPa.Using obtained elastic constants,the coefficients of the Landau potential are calculated to understand the phase transition between cubic and tetragonal.The calculated coefficients of the Landau potential are,λ2=3.12×10-2 GPa,λ4=-2.02×10-2 GPa,B*=1.34×10-4 GPa and B=1.66×10-4 GPa.The elastic results have profound implications in understanding the structure of the Earth's interior and indicate that the presence of tetragonal Ti-bearing CaSiO3 helps to explain the large ASPO of the Earth's mid-mantle.
文献关键词：
中图分类号：
作者姓名：
Caizi Zhang;Fangfei Li;Xinmiao Wei;Mengqi Guo;Yingzhan Wei;Liang Li;Xinyang Li;Qiang Zhou
作者机构：
State Key Laboratory of Superhard Materials,Jilin University,Changchun 130012,China;Synergetic Extreme Condition User Facility,Jilin University,Changchun 130012,China
文献出处：
引用格式：
[1]Caizi Zhang;Fangfei Li;Xinmiao Wei;Mengqi Guo;Yingzhan Wei;Liang Li;Xinyang Li;Qiang Zhou-.Abnormal Elastic Changes for Cubic-Tetragonal Transition of Single-Crystal SrTiO3)[J].中国物理快报（英文版）,2022(09):35-43
A类：
Tetragonal,davemaoite,ASPO
B类：
Abnormal,Elastic,Changes,Cubic,Transition,Single,Crystal,SrTiO3,Strontium,titanate,typical,perovskite,type,ceramic,oxide,studying,its,high,pressure,phases,are,critical,ferroelastic,transition,also,used,important,analog,CaSiO3,compositional,velocity,structure,Earth,interior,However,studies,cubic,tetragonal,properties,remain,unclear,Here,investigate,elasticity,single,crystal,by,Raman,Brillouin,scattering,combined,diamond,anvil,cell,acoustic,velocities,independent,constants,determined,up,GPa,room,temperature,This,indicates,that,C11,C12,C44,exhibit,abnormal,changes,which,related,Interestingly,significant,softening,shear,modulus,large,anisotropy,wave,splitting,jump,observed,Using,obtained,coefficients,Landau,potential,calculated,between,results,have,profound,implications,understanding,presence,bearing,helps,explain,mid,mantle
AB值：
0.513882
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