典型文献
Probing the Air Storage Failure Mechanism of Ni-Rich Layered Cathode Materials
文献摘要：
Ni-rich layered oxide cathode materials,such as LiNi0.83Co0.12Mn0.05O2(NCM811),exhibit high specific capacity and low cost,and become cathode material preference of high-energy-density Li-ion batteries.However,these cathode materials are not stable and will form Li-poor reconstructed layers and alkaline compounds(Li2CO3,LiOH)on the surface during the storage and processing in humid air,resulting in serious deterioration of elec-trochemical properties.During the past two decades,the consensus on the surface instability mechanism during humid air storage has not been reached.The main controversy focuses on the unstable octahedron mechanism and the Li/H exchange mechanism.Herein,we investigate the instability mechanism in the humid air by conducting scanning electronic microscopy,scanning transmission electron microscopy,and x-ray photoelectron spectroscopy analysis on NCM811 samples stored in designed atmospheres,etc.,and realize that the surface instability of the NCM811 during storage should be mainly originated from Li/H exchange when it contacts with moisture.
文献关键词：
中图分类号：
作者姓名：
Qingyu Dong;Ruowei Yi;Jizhen Qi;Yanbin Shen;Liwei Chen
作者机构：
i-Lab,CAS Center for Excellence in Nanoscience,Suzhou Institute of Nano-Tech and Nano-Bionics(SINANO),Chinese Academy of Sciences(CAS),Suzhou 215123,China;In Situ Center for Physical Sciences,School of Chemistry and Chemical Engineering,Shanghai Jiaotong University,Shanghai 200240,China
文献出处：
引用格式：
[1]Qingyu Dong;Ruowei Yi;Jizhen Qi;Yanbin Shen;Liwei Chen-.Probing the Air Storage Failure Mechanism of Ni-Rich Layered Cathode Materials)[J].中国物理快报（英文版）,2022(03):105-108
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B类：
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AB值：
0.651817
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