典型文献
Hydrogenation of CO2 to formate catalyzed by SBA-1 5-supported cyclic(alkyl)(amino)carbene-iridium
文献摘要：
Recently,cyclic(alkyl)(amino)carbenes(CAACs)have been widely used as ligands to enhance the cat-alytic reactivity of center metal,but the problem of recycling this expensive ligand remains to be solved.In this work,the heterogeneous SBA-15-CAAC-Ir catalyst was prepared by a covalent attachment method,and using SBA-15 as the carrier.It shows high reactivity for the hydrogenation of CO2 to formate.After immobilization,the ordered mesoporous structure and the overall rod-like morphology of the original SBA-15 have been preserved very well.Using SBA-15-CAAC-Ir as catalyst,up to 21050 TON can be obtained at 60℃.In addition,the catalyst can be separated easily by centrifugation,and the catalytic activity of SBA-15-CAAC-Ir can still remain very high after multiple cycles.
文献关键词：
中图分类号：
作者姓名：
Lei Zhou;Lingling Peng;Xingbang Hu
作者机构：
College of Chemistry and Chemical Engineering,Yangzhou Polytechnic Institute,Yangzhou 225127,China;School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210093,China
文献出处：
引用格式：
[1]Lei Zhou;Lingling Peng;Xingbang Hu-.Hydrogenation of CO2 to formate catalyzed by SBA-1 5-supported cyclic(alkyl)(amino)carbene-iridium)[J].中国化学工程学报（英文版）,2022(10):283-291
A类：
carbenes,CAACs
B类：
Hydrogenation,formate,catalyzed,by,SBA,supported,cyclic,alkyl,amino,iridium,Recently,have,been,widely,used,ligands,enhance,reactivity,center,metal,but,problem,recycling,this,expensive,remains,solved,In,work,heterogeneous,Ir,catalyst,was,prepared,covalent,attachment,method,using,carrier,It,shows,high,hydrogenation,After,immobilization,ordered,mesoporous,structure,overall,rod,like,morphology,original,preserved,very,well,Using,TON,can,obtained,addition,separated,easily,centrifugation,catalytic,still,after,multiple,cycles
AB值：
0.54317
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
