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典型文献
Superhigh selective capture of volatile organic compounds exploiting cigarette butts-derived engineering carbonaceous adsorbent
文献摘要:
Herein,we develop cost-efficient superhigh-performance of engineering carbonaceous adsorbent from cigarette butts using combined wet-impregnated and re-dispersed method of KOH,which optimizes the implant approach of activator,breaking the restriction of selective capture of toluene using tradi-tional activated carbon.The Brunauer-Emmett-Teller(BET)surface area and pore volume of targeted adsorbent can attain 3088 m2·g-1 and 1.61 cm3·g-1,respectively,by optimizing the temperature-dependent synthetic factor effect of the adsorbent.The adsorption capacity of resultant adsorbent for pre-senting volatile benzene and toluene shows a positive correlation with increasing carbonization temper-ature of carbon precursor.Besides,we demonstrated the unsmoked and smoked butts derived adsorbents afford feeble difference in saturated adsorbed capacity of volatile organic compounds(VOCs).The highest adsorption capacity of sample CF-800 for benzene and toluene in CF group is as high as 1268.1 and 1181.6 mg·g-1 respectively,slightly higher than that of sample UF-800,but far outperforming reported other adsorbents.The predicted adsorption selectivity of CF-800 and UF-800 for C7H8/H2O(g)using the DIH(difference of isosteric heats)equation reach up to ca.3800 and 7500 respectively,indicating the weak adsorbability of water vapor on the developed adsorbent and greater superiority of the smoked butts derived adsorbents in selective capture of VOCs at low relative humidity in the competitive adsorp-tion process for practical mixed VOCs.
文献关键词:
作者姓名:
Wenjian Zhu;Xuhua Shen;Rui Ou;Manoj Murugesan;Aihua Yuan;Jianfeng Liu;Xiaocai Hu;Zhen Yang;Ming Shen;Fu Yang
作者机构:
School of Environmental and Chemical Engineering,Jiangsu University of Science and Technology,Zhenjiang 212003,China;Marine Equipment and Technology Institute,Jiangsu University of Science and Technology,Zhenjiang 212003,China;Shanghai Waigaoqiao Shipbuilding Co.,Ltd,Shanghai 200137,China;School of Chemistry and Chemical Engineering,Yangzhou University,Yangzhou 212003,China;Jiangsu Agricultural Hormone Engineering Technology Research Center Co.Ltd,Changzhou 213022,China
引用格式:
[1]Wenjian Zhu;Xuhua Shen;Rui Ou;Manoj Murugesan;Aihua Yuan;Jianfeng Liu;Xiaocai Hu;Zhen Yang;Ming Shen;Fu Yang-.Superhigh selective capture of volatile organic compounds exploiting cigarette butts-derived engineering carbonaceous adsorbent)[J].中国化学工程学报(英文版),2022(06):194-206
A类:
Superhigh,butts,unsmoked,feeble,C7H8
B类:
selective,capture,volatile,organic,compounds,exploiting,cigarette,derived,engineering,carbonaceous,Herein,cost,efficient,superhigh,performance,from,using,combined,wet,impregnated,dispersed,method,KOH,which,optimizes,implant,approach,activator,breaking,restriction,toluene,tradi,tional,activated,Brunauer,Emmett,Teller,BET,surface,area,pore,volume,targeted,can,attain,cm3,respectively,by,optimizing,temperature,dependent,synthetic,effect,adsorption,capacity,resultant,senting,benzene,shows,positive,correlation,increasing,carbonization,precursor,Besides,demonstrated,adsorbents,afford,difference,saturated,adsorbed,VOCs,highest,sample,CF,group,slightly,higher,than,that,UF,far,outperforming,reported,other,predicted,selectivity,H2O,DIH,isosteric,heats,equation,reach,indicating,weak,adsorbability,water,vapor,developed,greater,superiority,low,relative,humidity,competitive,process,practical,mixed
AB值:
0.526657
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