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典型文献
Highly dispersible cerium-oxide modified Ni/SBA-15 for steam reforming of bio-mass based JP10
文献摘要:
Ni/SBA-15 modified by highly dispersed cerium-oxide was prepared with the aid of sucrose for steam reforming of JP10(C10H16).Their characterization showed that addition of appropriate amount ceria led to the formation of highly dispersed CeO2 and Ni,and the CeO2 covered smaller nickel particles like strawberry seeds to form much more interface between them.Their catalytic activity exhibited higher stability over time on stream of 6.5 h with conversion higher than 95%and higher carbon resistance(mass loss less than 4.5%by TG),which may derive from good properties below:(1)much more interface enhanced cooperation effect and increased turnover frequency at the interface;(2)the stronger interac-tion between Ni and ceria to suppress sintering by formation of Ni-O-Ce solid solution;(3)the large amount of oxygen vacancies from the formation of Ni-O-Ce solid solution and highly dispersed CeO2 to facilitate the water-gas-shift reaction and carbon removal.
文献关键词:
作者姓名:
Haocui Zhang;Zhourong Xiao;Mei Yang;Jijun Zou;Guozhu Liu;Xiangwen Zhang
作者机构:
Key Laboratory for Green Chemical Technology of Ministry of Education,School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China;Microchemical Engineering and Technology Group,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China
引用格式:
[1]Haocui Zhang;Zhourong Xiao;Mei Yang;Jijun Zou;Guozhu Liu;Xiangwen Zhang-.Highly dispersible cerium-oxide modified Ni/SBA-15 for steam reforming of bio-mass based JP10)[J].中国化学工程学报(英文版),2022(03):255-265
A类:
JP10,C10H16
B类:
Highly,dispersible,cerium,oxide,modified,SBA,steam,reforming,bio,mass,by,highly,dispersed,was,prepared,aid,sucrose,Their,characterization,showed,that,addition,appropriate,amount,ceria,led,formation,CeO2,covered,smaller,nickel,particles,like,strawberry,seeds,much,more,interface,between,them,catalytic,activity,exhibited,higher,stability,stream,conversion,than,carbon,resistance,loss,less,which,may,derive,from,good,properties,below,enhanced,cooperation,effect,increased,turnover,frequency,stronger,interac,suppress,sintering,solid,solution,large,oxygen,vacancies,facilitate,water,gas,shift,reaction,removal
AB值:
0.567536
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