典型文献
Photoelectrochemical oxygen atom transfer enabling efficient selective oxygenation
文献摘要：
Photoelectrochemical (PEC) technique represents a promis-ing approach to chemical transformation by harvesting sus-tainable solar energy.Despite the wide applications of PEC systems such as environmental remediation and solar energy conversion,the reported PEC reactions are dominated by the radical-based processes that are initiated by the single elec-tron transfer between photo-induced carriers and adsorbed species on photoelectrode surface [1,2].For instance,hy-droxyl radicals are often involved in the PEC oxidation re-actions.As well known,it is a grand challenge to control the formation and evolution rates of radicals,which inevitably leads to the unsatisfactory product selectivity of PEC reac-tions.Naturally,such a circumstance brings about a question to the research community whether a different mechanism can be established to sustain efficient and selective oxyge-nation.Recently,based on their previous findings on PEC water oxidation [3,4],Zhao and coworkers [5] reported that many substrates can be oxidized in an oxygen atom transfer(OAT) pathway,a non-radical two electron process,to oxy-genated products by α-Fe2O3 photoanodes.
文献关键词：
中图分类号：
作者姓名：
Yujie Xiong
作者机构：
School of Chemistry and Materials Science,University of Science and Technology of China,Hefei 230026,China
文献出处：
引用格式：
[1]Yujie Xiong-.Photoelectrochemical oxygen atom transfer enabling efficient selective oxygenation)[J].中国科学:化学（英文版）,2022(01):5-6
A类：
droxyl,oxyge
B类：
Photoelectrochemical,atom,transfer,enabling,efficient,selective,oxygenation,PEC,technique,represents,promis,approach,transformation,by,harvesting,tainable,solar,energy,Despite,wide,applications,systems,such,environmental,remediation,conversion,reported,reactions,are,dominated,processes,that,initiated,single,between,induced,carriers,adsorbed,species,photoelectrode,surface,For,instance,hy,radicals,often,involved,oxidation,well,known,grand,challenge,control,evolution,which,inevitably,leads,unsatisfactory,selectivity,Naturally,circumstance,brings,about,question,research,community,whether,different,mechanism,can,established,sustain,Recently,their,previous,findings,water,Zhao,coworkers,many,substrates,oxidized,OAT,pathway,two,electron,genated,products,Fe2O3,photoanodes
AB值：
0.583073
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
