典型文献
Perforated nitrogen-rich graphene-like carbon nanolayers supported Cu-In catalyst for boosting CO2 electroreduction to CO
文献摘要：
The combination of a powerful CO2-enriching carrier and robust active component provides a new idea for the construction of efficient catalysts for electrocatalytic CO2 reduction.Herein,novel perforated nitrogen-rich graphene-like carbon nanolayers(PNGC)are prepared from biomass derivatives,which promotes the oriented deposition of In-doped Cu2(OH)3(NO3)nanosheet patches.A robust Cu-In/PNGC composite catalyst is then obtained via simple in-situ electrochemical reduction.Unsurprisingly,Cu-In/PNGC exhibits a CO Faradaic efficiency(FEco)of 91.3％and a remarkable CO partial current density(jco)of 136.4 mA cm-2 at a moderate overpotential of 0.59 V for electrocatalytic CO2 reduction reaction(CO2RR).DFT calculations and experimental studies indicate that the strong carrier effect of PNGC makes PNGC carried Cu-In nanosheets improved the adsorption capacity of CO2 gas,reconfigured electronic structure,and reduced free energy of key intermediate formation,thereby the CO2 activation and conver-sion are promoted.
文献关键词：
中图分类号：
作者姓名：
Xinxin Zhang;Yuxiao Zhu;Ziyong Liu;Fuli Li;Wei Zhou;Zichao Dong;Jingxin Fan;Licheng Liu;Chunhua Du
作者机构：
Laboratory of Reaction and Separation Technology,Qingdao Agricultural University,Qingdao 266109,Shandong,China;CAS Key Laboratory of Bio-based Materials,Qingdao Institute of Bioenergy and Bioprocess Technology,Chinese Academy of Sciences,Qingdao 266101,Shandong,China;CenterTech Tianjin Chemical Research and Design Institute Co.,Ltd.,Tianjin 300131,China
文献出处：
引用格式：
[1]Xinxin Zhang;Yuxiao Zhu;Ziyong Liu;Fuli Li;Wei Zhou;Zichao Dong;Jingxin Fan;Licheng Liu;Chunhua Du-.Perforated nitrogen-rich graphene-like carbon nanolayers supported Cu-In catalyst for boosting CO2 electroreduction to CO)[J].能源化学,2022(12):383-390
A类：
PNGC,Unsurprisingly,jco
B类：
Perforated,nitrogen,graphene,like,carbon,nanolayers,supported,In,boosting,electroreduction,combination,powerful,enriching,carrier,robust,active,component,provides,new,idea,construction,efficient,catalysts,electrocatalytic,Herein,novel,perforated,prepared,from,biomass,derivatives,which,promotes,oriented,deposition,doped,Cu2,NO3,patches,composite,then,obtained,via,simple,situ,electrochemical,exhibits,Faradaic,efficiency,FEco,remarkable,partial,current,density,mA,moderate,overpotential,reaction,CO2RR,DFT,calculations,experimental,studies,indicate,that,strong,effect,makes,carried,nanosheets,improved,adsorption,capacity,gas,reconfigured,electronic,structure,reduced,free,energy,key,intermediate,formation,thereby,activation,conver,sion,promoted
AB值：
0.623476
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