典型文献
Electrochemical lithium ions pump for lithium recovery from brine by using a surface stability Al2O3-ZrO2 coated LiMn2O4 electrode
文献摘要:
The rapid commercialization of lithium-ion batteries has caused significant expansion of the lithium demand.Electrochemical lithium ions pump is a promising technology because of its good selectivity and friendly environment.Herein,an Al2O3-ZrO2 film coating of the LiMn2O4(AlZr-LMO)electrode is prepared and operated for recovery of Li+from brine.The Li+maximum extraction capacity of AlZr-LMO reached 49.92 mg/g in one cycle.Compared with the solely LMO electrode,the AlZr-LMO demon-strated evident electrochemical stability and cycle life towards the Li+recovery system.After 30 succes-sive cycles,the extraction capacity for Li+increased from 29.21%to 57.67%.The high cycle capacity of the material could be attributed to its low polarization,high active sites,and good chemical stability of the electrode surface owing to the synergy function of Al2O3-ZrO2 in the charging-discharging process.A dynamic model parameter identification method was performed to evaluate the active site of AlZr-LMO.This work may provide a way to design the AlZr-LMO electrode and develop a good method for the recovery of lithium from brine.
文献关键词:
中图分类号:
作者姓名:
Guiling Luo;Lin Zhu;Xiaowei Li;Guolang Zhou;Jing Sun;Linlin Chen;Yanhong Chao;Lei Jiang;Wenshuai Zhu
作者机构:
School of the Environment and Safety Engineering,Jiangsu University,Zhenjiang 212013,Jiangsu,China;College of Chemistry and Chemical Engineering,Hainan Normal University,Haikou 571158,Hainan,China;School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang 212013,Jiangsu,China;School of Pharmacy,Jiangsu University,Zhenjiang 212013,Jiangsu,China;Jiangsu Topfine New Materials Technology Co.Ltd.,Zhenjiang 212009,Jiangsu,China
文献出处:
引用格式:
[1]Guiling Luo;Lin Zhu;Xiaowei Li;Guolang Zhou;Jing Sun;Linlin Chen;Yanhong Chao;Lei Jiang;Wenshuai Zhu-.Electrochemical lithium ions pump for lithium recovery from brine by using a surface stability Al2O3-ZrO2 coated LiMn2O4 electrode)[J].能源化学,2022(06):244-252
A类:
AlZr,Li+from,Li+maximum,Li+recovery,Li+increased
B类:
Electrochemical,lithium,ions,pump,brine,by,using,surface,stability,Al2O3,ZrO2,coated,LiMn2O4,electrode,rapid,commercialization,batteries,has,caused,significant,expansion,demand,promising,technology,because,its,good,selectivity,friendly,environment,Herein,film,coating,LMO,prepared,operated,extraction,capacity,reached,one,Compared,solely,demon,strated,evident,electrochemical,life,towards,system,After,succes,sive,cycles,high,material,could,attributed,low,polarization,active,sites,owing,synergy,function,discharging,process,dynamic,model,parameter,identification,method,was,performed,evaluate,This,work,may,provide,way,design,develop
AB值:
0.463344
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