典型文献
Ultrasmall AuPd nanoclusters on amine-functionalized carbon blacks as high-performance bi-functional catalysts for ethanol electrooxidation and formic acid dehydrogenation
文献摘要：
The synthesis of ultrasmall metal nanoclusters(NCs)with high catalytic activities is of great importance for the development of clean and renewable energy technologies but remains a challenge.Here we report a facile wet-chemical method to prepare～1.0 nm AuPd NCs supported on amine-functionalized carbon blacks.The AuPd NCs exhibit a specific activity of 5.98 mA cmAuPd and mass activity of 5.25 A mgAuPd for ethanol electrooxidation,which are far better than those of commercial Pd/C catalysts(1.74 mA cmPd2 and 0.54 A mgPd-1).For formic acid dehydrogenation,the AuPd NCs have an initial turn over frequency of 49339 h1 at 298 K without any additive,which is much higher than those obtained for most of reported AuPd catalysts.The reported synthesis may represent a facile and low-cost approach to prepare other ultrasmall metal NCs with high catalytic activities for various applications.
文献关键词：
中图分类号：
作者姓名：
Yuhuan Cui;Ming Zhao;Yining Zou;Junyu Zhang;Jiuhui Han;Zhili Wang;Qing Jiang
作者机构：
Key Laboratory of Automobile Materials,Ministry of Education,School of Materials Science and Engineering,Jilin University,Changchun 130022,Jilin,China;Frontier Research Institute for Interdisciplinary Sciences(FRIS),Tohoku University,Sendai 980-8578,Japan
文献出处：
引用格式：
[1]Yuhuan Cui;Ming Zhao;Yining Zou;Junyu Zhang;Jiuhui Han;Zhili Wang;Qing Jiang-.Ultrasmall AuPd nanoclusters on amine-functionalized carbon blacks as high-performance bi-functional catalysts for ethanol electrooxidation and formic acid dehydrogenation)[J].能源化学,2022(05):556-563
A类：
cmAuPd,mgAuPd,cmPd2,mgPd
B类：
Ultrasmall,nanoclusters,amine,functionalized,carbon,blacks,performance,catalysts,ethanol,electrooxidation,formic,acid,dehydrogenation,synthesis,ultrasmall,metal,NCs,catalytic,activities,great,importance,development,clean,renewable,energy,technologies,but,remains,challenge,Here,facile,wet,chemical,method,prepare,supported,exhibit,specific,activity,mass,which,far,better,those,commercial,For,have,initial,turn,over,frequency,h1,without,any,additive,much,higher,obtained,most,reported,may,represent,low,cost,approach,other,various,applications
AB值：
0.470019
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
