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典型文献
Direct and green repairing of degraded LiCoO2 for reuse in lithium-ion batteries
文献摘要:
Traditional recycling processes of LiCoO2 rely on destructive decomposition,requiring high-temperature roasting or acid leaching to extract valuable Li and Co,which have significant environmental and economic concerns.Herein,a direct repairing method for degraded LiCoO2 using a LiCl-CH4N2O deep eutectic solvent(DES)was established.The DES is not used to dissolve LiCoO2 but directly serves as a carrier for the selective replenishment of lithium and cobalt.Replenishment of lithium restores LiCoO2 at different states of charge to a capacity of 130 mAh/g(at 0.1 C rate),while replenishing the cobalt increases the capacity retention rate of 90%after 100 cycles,which is comparable to pristine LiCoO2.The DES is collected and reused multiple times with a high repair efficiency.This process reduces energy consumption by 37.1%and greenhouse gas emissions by 34.8%compared with the current production process of LiCoO2,demonstrating excellent environmental and economic viability.
文献关键词:
作者姓名:
Junxiong Wang;Qi Zhang;Jinzhi Sheng;Zheng Liang;Jun Ma;Yuanmao Chen;Guangmin Zhou;Hui-Ming Cheng
作者机构:
Shenzhen Geim Graphene Center,Tsinghua-Berkeley Shenzhen Institute&Tsinghua Shenzhen International Graduate School,Tsinghua University,Shenzhen 518055,China;Frontiers Science Center for Transformative Molecules,School of Chemistry and Chemical Engineering,Shanghai Jiao Tong University,Shanghai 200240,China;Faculty of Materials Science and Engineering/Institute of Technology for Carbon Neutrality,Shenzhen Institute of Advanced Technology,Chinese Academy of Sciences,Shenzhen 518055,China
引用格式:
[1]Junxiong Wang;Qi Zhang;Jinzhi Sheng;Zheng Liang;Jun Ma;Yuanmao Chen;Guangmin Zhou;Hui-Ming Cheng-.Direct and green repairing of degraded LiCoO2 for reuse in lithium-ion batteries)[J].国家科学评论(英文版),2022(08):118-128
A类:
Replenishment
B类:
Direct,repairing,degraded,LiCoO2,lithium,batteries,Traditional,recycling,processes,rely,destructive,decomposition,requiring,high,temperature,roasting,acid,leaching,extract,valuable,which,have,significant,environmental,economic,concerns,Herein,method,using,LiCl,CH4N2O,deep,eutectic,solvent,DES,was,established,not,dissolve,but,directly,serves,carrier,selective,replenishment,cobalt,restores,different,states,charge,capacity,mAh,rate,while,replenishing,increases,retention,after,cycles,comparable,pristine,collected,reused,multiple,times,efficiency,This,reduces,energy,consumption,by,greenhouse,gas,emissions,compared,current,production,demonstrating,excellent,viability
AB值:
0.617482
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