典型文献
Inactive Al3+-doped La(CoCrFeMnNiAlx)1/(5+x)O3 high-entropy perovskite oxides as high performance supercapacitor electrodes
文献摘要:
A series of high-entropy perovskite oxides(HEPOs)La(CoCrFeMnNiAlx)1/(5+x)O3-δ(x=0.4,0.5,0.6,and 0.7)have been synthesized by coprecipitation method combined with calcination process and explored as electrodes for supercapacitors.The crystal structure,microstructure,and elemental composition of HEPOs were investigated by X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),and energy-dispersive X-ray spectroscopy(EDS)in detail.The electrochemical properties of HEPOs as supercapacitor electrodes were elucidated.The specific capacitances of HEPOs(x=0.4,0.5,0.6,and 0.7)are 281.84,353.65,325.60,and 259.30 F/g at the current density of 1 A/g,respectively.After 2000 cycles,the specific capacitances of HEPOs(x=0.4,0.5,0.6,and 0.7)remain 85.01%,88.61%,86.37%,and 91.25%,respectively.Such outstanding electrochemical properties can be attributed to the entropy-stabilized structure caused by mixed six cations in B-site and the Al3+-doping suppressing active ion aggregation during charge-discharge process.This research highlights the potential of HEPOs as electrodes for supercapacitors.
文献关键词:
中图分类号:
作者姓名:
Meng GUO;Yufeng LIU;Fengnian ZHANG;Fuhao CHENG;Chufei CHENG;Yang MIAO;Feng GAO;Jun YU
作者机构:
College of Materials Science and Engineering,Taiyuan University of Technology,Taiyuan 030024,China
文献出处:
引用格式:
[1]Meng GUO;Yufeng LIU;Fengnian ZHANG;Fuhao CHENG;Chufei CHENG;Yang MIAO;Feng GAO;Jun YU-.Inactive Al3+-doped La(CoCrFeMnNiAlx)1/(5+x)O3 high-entropy perovskite oxides as high performance supercapacitor electrodes)[J].先进陶瓷(英文版),2022(05):742-753
A类:
Inactive,CoCrFeMnNiAlx,5+x,HEPOs
B类:
Al3+,doped,La,O3,entropy,perovskite,oxides,as,performance,electrodes,series,have,been,synthesized,by,coprecipitation,method,combined,calcination,process,explored,supercapacitors,crystal,microstructure,elemental,composition,were,investigated,ray,diffraction,scanning,electron,microscopy,transmission,TEM,energy,dispersive,spectroscopy,EDS,detail,electrochemical,properties,elucidated,specific,capacitances,are,current,density,respectively,After,cycles,remain,Such,outstanding,attributed,stabilized,caused,mixed,six,cations,site,doping,suppressing,aggregation,during,discharge,This,research,highlights,potential
AB值:
0.482123
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