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典型文献
Amino-functionalized carbon nanotubes/polyphosphazene hybrids for improving the fire safety and mechanical properties of epoxy
文献摘要:
To expand further modern industrial applications of epoxy resin(EP),the urgent problems of flammability and poor mechanical properties have to be solved.Therefore,amino-functionalized carbon nanotubes(AFP@CNTs)was designed and successfully synthesized to enhance the comprehensive properties,including fire safety and mechanical properties.Especially,the flame retardant mechanism,the combustion and pyrolysis process of EP/AFP@CNTs were investigated as well.With the addition of 1.5 wt%AFP@CNTs,the peak heat release rate(PHRR)and total heat release(THR)of EP were reduced by 27.6%and 29.0%,respectively,which may due to the cooperative effect between the phosphorus-nitrogen synergistic flame retardant of polyphosphazene and the cohesive phase flame retardant of carbon nanotubes.In addition,the mechanical performance of EP/AFP@CNTs composites were also investigated.The results showed that the impact strength,tensile strength and the storage modulus effectively increased by 65.0%,29.0%and 13.2%,respectively.Meanwhile,the change of the combustion and pyrolysis process of EP/AFP@CNTs may be attributed to the catalytic effect of the amino-functionalized polyphosphazene,which could participate in the formation of epoxy thermal curing crosslinking network and catalyze the degradation process of epoxy resin.
文献关键词:
作者姓名:
Mutian Zhou;Desen Zeng;Shuilai Qiu;Xia Zhou;Liang Cheng;Zhoumei Xu;Weiyi Xing;Yuan Hu
作者机构:
State Key Laboratory of Fire Science,University of Science and Technology of China,96 Jinzhai Road,Hefei,Anhui,230026,China;Innovation Center,Midea Residential Air Conditioner Division,Midea Group,China
引用格式:
[1]Mutian Zhou;Desen Zeng;Shuilai Qiu;Xia Zhou;Liang Cheng;Zhoumei Xu;Weiyi Xing;Yuan Hu-.Amino-functionalized carbon nanotubes/polyphosphazene hybrids for improving the fire safety and mechanical properties of epoxy)[J].自然科学进展·国际材料(英文),2022(02):179-189
A类:
polyphosphazene
B类:
Amino,functionalized,carbon,nanotubes,hybrids,improving,fire,safety,mechanical,properties,epoxy,To,expand,further,modern,industrial,applications,resin,EP,urgent,problems,flammability,poor,have,solved,Therefore,amino,AFP,CNTs,was,designed,successfully,synthesized,enhance,comprehensive,including,Especially,flame,retardant,mechanism,combustion,pyrolysis,process,were,investigated,well,With,addition,wt,peak,heat,release,rate,PHRR,total,THR,reduced,by,respectively,which,may,due,cooperative,between,phosphorus,nitrogen,synergistic,cohesive,phase,In,performance,composites,also,results,showed,that,impact,strength,tensile,storage,modulus,effectively,increased,Meanwhile,change,attributed,catalytic,could,participate,formation,thermal,curing,crosslinking,network,catalyze,degradation
AB值:
0.538378
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