典型文献
Tuning Solvent Composition to Enhance the Stability of Metal Clusters in Mass Spectrometry
文献摘要：
Electrospray ionization time-of-flight mass spectrometry(ESI-TOF-MS)has been recognized as a powerful technique for studying metal clusters'chemical composition and reaction mechanisms.It is a great chal-lenge in mass spectrometry analysis to maintain the metal cluster molecules intact without fragmentation,which is achieved in this work by using mixed solvents to change the interaction between cluster molecules and solvent molecules,further affecting the fragmentation behaviors of the metal cluster in MS.Theoretical analysis reveals that the stability of the[(C)Au6Ag2(C18H14ONP)6]4+cluster in ESI-TOF-MS is related to the strength of the chemical bonds between its own atoms and the bonding between the solvent and the cluster molecules.
文献关键词：
中图分类号：
作者姓名：
Yingzi Han;Yihuang Jiang;Jing Jeanne Yang;Shuichao Lin;Zichao Tang;Lansun Zheng
作者机构：
State Key Laboratory of Physical Chemistry of Solid Surface,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China
文献出处：
引用格式：
[1]Yingzi Han;Yihuang Jiang;Jing Jeanne Yang;Shuichao Lin;Zichao Tang;Lansun Zheng-.Tuning Solvent Composition to Enhance the Stability of Metal Clusters in Mass Spectrometry)[J].结构化学,2022(04):34-39
A类：
Au6Ag2,C18H14ONP,4+cluster
B类：
Tuning,Solvent,Composition,Enhance,Stability,Metal,Clusters,Mass,Spectrometry,Electrospray,ionization,flight,mass,spectrometry,ESI,TOF,has,been,recognized,powerful,technique,studying,metal,clusters,chemical,composition,reaction,mechanisms,It,great,chal,lenge,analysis,maintain,molecules,intact,without,fragmentation,which,achieved,this,work,by,using,mixed,solvents,change,interaction,between,further,affecting,behaviors,Theoretical,reveals,that,stability,related,strength,bonds,its,own,atoms,bonding
AB值：
0.595434
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