典型文献
Preheat Compression Molding for Polyetherketoneketone:Effect of Molecular Mobility
文献摘要:
Polyetherketoneketone (PEKK) is a new evolving polymeric material,and is considered as another important member of the polyaryletherketone (PAEK) family in addition to polyetheretherketone (PEEK).Hot compression molding can be used to compact and consolidate the PEKK products,where the temperature and pressure play key roles to affect the molecular mobility,entanglement and crystallization,and thus the mechanical properties of PEKKs.In this study,a preheating treatment was introduced in the compression molding,and it is found that such preheating is very essential to avoid the formation of crystal Form Ⅱ,based on the increased chain entanglement.Molecular dynamics simulations revealed that the molecular mobility is always suppressed when a compression is applied.Therefore,by increasing the entanglement via the preheating and maintaining such entanglement in the consequent compression molding,strong and tough PEKK materials were obtained,with a negligible fraction of crystal Form Ⅱ.
文献关键词:
中图分类号:
作者姓名:
Xiao-Hua Zhang;Meng-Xiao Jiao;Xin Wang;Bo-Lan Li;Feng Zhang;Yan-Bo Li;Jing-Na Zhao;He-Hua Jin;Yu Yang
作者机构:
Key Laboratory of Textile Science & Technology (Ministry of Education),College of Textiles,and Innovation Center for Textile Science and Technology,Donghua University,Shanghai 201620,China;Advanced Materials Division,Suzhou Institute of Nano-Tech and Nano-Bionics,Chinese Academy of Sciences,Suzhou 215123,China;Key Laboratory of Carbon Materials,National Engineering Laboratory for Carbon Fiber Technology,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan 030001,China
文献出处:
引用格式:
[1]Xiao-Hua Zhang;Meng-Xiao Jiao;Xin Wang;Bo-Lan Li;Feng Zhang;Yan-Bo Li;Jing-Na Zhao;He-Hua Jin;Yu Yang-.Preheat Compression Molding for Polyetherketoneketone:Effect of Molecular Mobility)[J].高分子科学(英文版),2022(02):175-184
A类:
Preheat,Polyetherketoneketone,polyaryletherketone,PEKKs
B类:
Compression,Molding,Effect,Molecular,Mobility,new,evolving,polymeric,considered,another,important,member,PAEK,family,addition,polyetheretherketone,PEEK,Hot,compression,molding,can,used,compact,consolidate,products,where,temperature,pressure,play,key,roles,affect,molecular,mobility,entanglement,crystallization,thus,mechanical,properties,In,this,study,preheating,treatment,was,introduced,found,that,such,very,essential,avoid,formation,Form,increased,chain,dynamics,simulations,revealed,always,suppressed,when,applied,Therefore,by,increasing,via,maintaining,consequent,strong,tough,materials,were,obtained,negligible,fraction
AB值:
0.554757
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机标中图分类号,由域田数据科技根据网络公开资料自动分析生成,仅供学习研究参考。