典型文献
Organophosphate esters in sediment from Taihu Lake,China:Bridging the gap between riverine sources and lake sinks
文献摘要:
Surface sediment samples from Taihu Lake in China and its inflow rivers,along with two lake sediment core samples,were collected and analyzed for organophosphate esters(OPEs).The concentrations of total OPEs varied from 28.60 ng/g to 158.72 ng/g(median:54.25 ng/g)in river surface sediment and from 62.57 ng/g to 326.84 ng/g(median:86.37 ng/g)in lake sediment.Tributyl phosphate(TnBP)was the predominant compound in river surface sediment,and tris(2-butoxyethyl)phosphate was predominant in lake sediment.High contamination occurred in the north-west region,which was related to the high level of urbanization and high usage of OPEs.The sediment-water partition coefficients of OPEs(logKoc)were calculated,showing a significant correlation with logKow(p<0.05).The concentration and composition of OPEs in two sediment cores varied due to the different sampling locations,with more OPE species found in the northern region than in the southern one.Principal component analysis and positive matrix factorization indicated that sewage discharges,vehicle emissions,and atmospheric deposition were the possible sources of OPEs in Taihu Lake sediments.Tris(l-chloro-2-propyl)phosphate,tris(2-chloroethyl)phosphate,and TnBP were the main OPEs causing ecological risks.
文献关键词:
中图分类号:
作者姓名:
Wenping Zhang;Changsheng Guo;Jiapei Lv;Xu Li;Jian Xu
作者机构:
State Key Laboratory of Environmental Criteria and Risk Assessment,Chinese Research Academy of Environmental Sciences,Beijing 100012,China;State Environmental Protection Key Laboratory of Ecological Effect and Risk Assessment of Chemicals,Chinese Research Academy of Environmental Sciences,Beijing 100012,China;Center for Environmental Health Risk Assessment and Research,Chinese Research Academy of Environmental Sciences,Beijing 100012,China
文献出处:
引用格式:
[1]Wenping Zhang;Changsheng Guo;Jiapei Lv;Xu Li;Jian Xu-.Organophosphate esters in sediment from Taihu Lake,China:Bridging the gap between riverine sources and lake sinks)[J].环境科学与工程前沿,2022(03):33-45
A类:
Tributyl,TnBP,logKoc,logKow
B类:
Organophosphate,esters,from,Taihu,Lake,China,Bridging,gap,between,riverine,sources,lake,sinks,Surface,samples,its,inflow,rivers,along,two,were,collected,analyzed,organophosphate,OPEs,concentrations,total,varied,median,surface,was,predominant,compound,tris,butoxyethyl,High,contamination,occurred,west,region,which,related,high,level,urbanization,usage,water,partition,coefficients,calculated,showing,significant,correlation,composition,cores,due,different,sampling,locations,more,species,found,northern,than,southern,Principal,component,analysis,positive,matrix,factorization,indicated,that,sewage,discharges,vehicle,emissions,atmospheric,deposition,possible,sediments,Tris,propyl,chloroethyl,main,causing,ecological,risks
AB值:
0.493942
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