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典型文献
Carbon hollow spheres as cocatalyst of Cu-doped TiO2 nanoparticles for improved photocatalytic H2 generation
文献摘要:
The reasonable employment of cocatalyst in photocatalysis can effectively promote the photocatalytic H2 production activity.In this study,carbon hollow spheres(C),as a good conductive nonmetallic material,have been utilized as a novel cocatalyst and a matrix for loading the Cu-doped-TiO2 nanoparticles by a successive hydrother-mal method and metal molten salt method.The Cu-doped-TiO2 nanoparticles were tightly anchored on the surface of carbon hollow sphere to form a zero-dimensional/three dimensional(0D/3D)Cu-doped-TiO2/C heterojunction.The optimal Cu-doped-TiO2/C heterojunction demon-strated greatly enhanced photocatalytic H2 generation activity(14.4 mmol·g-1·h-1)compared with TiO2(0.33 mmol·g-1·h-1)and TiO2/C(0.7 mmol·g-1·h-1).The performance improvement was mainly due to the syner-gistic effect of carbon hollow sphere cocatalyst and Cu-doping,the Cu-doping in TiO2 nanoparticles can minimize charge recombination and enhance the available photoex-cited electrons,while the 3D carbon hollow spheres can act as electron traps to accelerate the charge separation and offer abundant active sites for solar water splitting reaction.
文献关键词:
作者姓名:
Li-Juan Sun;Hai-Wei Su;Di-Fa Xu;Le-Le Wang;Hua Tang;Qin-Qin Liu
作者机构:
School of Materials Science and Engineering,Jiangsu University,Zhenjiang 212013,China;Hunan Key Laboratory of Applied Environmental Photocatalysis,Changsha University,Changsha 410022,China;State Key Laboratory of Photocatalysis on Energy and Environment,College of Chemistry,Fuzhou University,Fuzhou 350108,China;School of Environmental Science and Engineering,Qingdao University,Qingdao 266071,China
引用格式:
[1]Li-Juan Sun;Hai-Wei Su;Di-Fa Xu;Le-Le Wang;Hua Tang;Qin-Qin Liu-.Carbon hollow spheres as cocatalyst of Cu-doped TiO2 nanoparticles for improved photocatalytic H2 generation)[J].稀有金属(英文版),2022(06):2063-2073
A类:
photoex
B类:
Carbon,hollow,spheres,cocatalyst,doped,TiO2,nanoparticles,improved,photocatalytic,H2,generation,reasonable,employment,photocatalysis,can,effectively,promote,production,activity,In,this,study,carbon,good,conductive,nonmetallic,material,have,been,utilized,novel,matrix,loading,by,successive,hydrother,method,molten,salt,were,tightly,anchored,surface,zero,dimensional,three,0D,heterojunction,optimal,demon,strated,greatly,enhanced,compared,performance,improvement,was,mainly,due,syner,gistic,doping,minimize,charge,recombination,available,cited,electrons,while,traps,accelerate,separation,offer,abundant,active,sites,solar,water,splitting,reaction
AB值:
0.526556
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