典型文献
Design strategy for low-temperature sulfur etching to achieve high-performance hollow multifunctional electrode material
文献摘要:
Zeolite Imidazole Framework(ZIF)has the advantages of large specific surface area,high porosity,and easy functionalization,so it looked like one of the most promising energy storage and conversion ma-terials.In the meantime,transition metal oxides and sulfides have been widely used in environmen-tal and energy conversion applications.Hence,a NaOH-assisted thioacetamide etching strategy is,there-fore,designed with the metal-organic framework as precursor to realize the hollow nanostructure of ZIF bimetallic sulfide(Sx-CoCd-350)with abundant sulfur vacancies for enhanced catalysts oxygen evolution reaction(OER)/hydrogen evolution reaction(HER))performance and capacitance performance of capaci-tor.The overpotential of S2-CoCd-350 in the OER process is 355 mV at 50 mA cm-2,which is substantially lower than other reported ZIF-based catalysts.S2-CoCd-350 has an overpotential of 84 mV at 10 mA cm-2 when employed as HER catalyst.Furthermore,the S2-CoCd-350 electrode did not alter appreciably during a long-term durability test of more than 10 h.More impressively,S2-CoCd-350 matches the activated car-bon(AC)electrode with excellent capacitance performance 1220 μWh cm-2 energy density(at 3370 μW cm2)and 25,000 μW cm-2(at 700 μWh cm-2)maximum power density.In addition,the assembled supercapacitor has excellent cycling stability.
文献关键词:
中图分类号:
作者姓名:
Hui Wen;Ziyu Yi;Zhenyu Hu;Rui Guo;Xuanwen Liu
作者机构:
School of Materials Science and Engineering,Northeastern University,Shenyang 110819,China;School of Resources and Materials,Northeastern University at Qinhuangdao,Qinhuangdao 066004,China
文献出处:
引用格式:
[1]Hui Wen;Ziyu Yi;Zhenyu Hu;Rui Guo;Xuanwen Liu-.Design strategy for low-temperature sulfur etching to achieve high-performance hollow multifunctional electrode material)[J].材料科学技术(英文版),2022(24):209-218
A类:
CoCd
B类:
Design,strategy,temperature,sulfur,etching,achieve,high,performance,hollow,multifunctional,electrode,material,Zeolite,Imidazole,Framework,ZIF,has,advantages,large,specific,surface,area,porosity,easy,functionalization,looked,like,one,most,promising,energy,storage,conversion,terials,In,meantime,transition,oxides,sulfides,have,been,widely,used,environmen,applications,Hence,NaOH,assisted,thioacetamide,there,fore,designed,organic,framework,precursor,realize,nanostructure,bimetallic,Sx,abundant,vacancies,enhanced,catalysts,oxygen,evolution,reaction,OER,hydrogen,HER,capacitance,overpotential,S2,process,mV,mA,which,substantially,lower,than,other,reported,when,employed,Furthermore,did,not,alter,appreciably,during,long,term,durability,test,More,impressively,matches,activated,car,bon,AC,excellent,Wh,density,maximum,power,addition,assembled,supercapacitor,cycling,stability
AB值:
0.588751
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